Chemical Communications 2012-04-04

Expanding the regioselective enzymatic repertoire: oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta.

Caroline E Paul, Aashrita Rajagopalan, Iván Lavandera, Vicente Gotor-Fernández, Wolfgang Kroutil, Vicente Gotor

Index: Chem. Commun. (Camb.) 27th ed., 48 , 3303-3305, (2012)

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Abstract

The first report of a biocatalytic regioselective oxidative mono-cleavage of dialkenes was successfully achieved employing a cell-free enzyme preparation from Trametes hirsuta at the expense of molecular oxygen. Selected reactions were performed on a preparative scale affording high to excellent conversions and chemoselectivities.

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