PNAS 1983-11-01

Oxygenation of hydrocarbons by cytochrome P-450 model compounds: modification of reactivity by axial ligands.

J P Collman, T Kodadek, S A Raybuck, B Meunier

Index: Proc. Natl. Acad. Sci. U. S. A. 80(22) , 7039-41, (1983)

Full Text: HTML

Abstract

The rate of olefin oxygenation catalyzed by synthetic metalloporphyrins is examined, employing sodium hypochlorite as the oxygen atom source. The rate of epoxidation and the stability of the catalyst are shown to be dependent on the nature of the axial ligand employed. A rationale for this effect is presented and analogy is made to the role of the thiolate ligand in cytochrome P-450.

Related Compounds

  • 3-Phenylpyridine

Related Articles:

Raman excitation profiles and excited state molecular configurations of three isomeric phenyl pyridines.

2000-04-01

[Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 56(5) , 855-75, (2000)]

Surface-enhanced Raman spectroscopy studies of phenylpyridines interacting with a copper electrode surface. Zawada K and Bukowska J.

[Surface Science 507 , 34-9, (2002)]

1H, 13C and 15N nuclear magnetic resonance coordination shifts in Au(III), Pd(II) and Pt(II) chloride complexes with phenylpyridines.

2009-08-01

[Magn. Reson. Chem. 47(8) , 658-65, (2009)]

Structure based development of phenylimidazole-derived inhibitors of indoleamine 2,3-dioxygenase.

2008-08-28

[J. Med. Chem. 51 , 4968-77, (2008)]

SCH 530348: a novel oral thrombin receptor antagonist.

2003-12-01

[Future Cardiol. 5(5) , 435-42, (2009)]

More Articles...