Reactions of amines. 20. Syntheses of racemic and optically active alkylhydrazines and N-acyl-N-alkyl-and N-acyl-N-arylhydrazines

HE Baumgarten, PYN Chen, HW Taylor…

Index: Baumgarten,H.E. et al. Journal of Organic Chemistry, 1976 , vol. 41, p. 3805 - 3811

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Citation Number: 27

Abstract

(18) A referee has suggested that the results with the methyl halide Grignard reagents which show yields of 4cw in the order I< Br< CI (and the high yield of 4cw with dimethylmagnesium) may be indicative of a single electron transfer mechanism. He suggests further that the effect of ferric chloride may also indicate a SET mechanism and wonders what the reaction with the tert-butyl chloride Grignard reaction might reveal. ...