Journal of the American Chemical Society

Bolaform Electrolytes. 1 II. Conductance of 1, 3-, 1, 4-and 1, 5-Di-(trimethylammonium)-polymethylene Halides in Water and in Methanol2

RM Fuoss, VFH Chu

Index: Fuoss; Chu Journal of the American Chemical Society, 1951 , vol. 73, p. 949

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Citation Number: 45

Abstract

Conductance at 25" in water and in methanol of the following salts have been measured: Br'(Me3N+(CH&N+ Mes) Br',(MeaN+(CH&N+ Me3) I', I'(Me3Pi+(CH2) 2V+ Me3) 1'and I'(Me3Nt (CHz) sN+ Mea) I'. Analysis of the conductance curves by the method of Fuoss and Edelson shows that there is some association (ka= 0.1) of one halide ion to the doubly charged cation in water, and considerable association (K?= 0. CKIl) in methanol. The ...