Inorganic Chemistry

Deprotonation of molybdenum carbonyl hydrido diphosphine [HMo (CO) 2 (PP) 2] BF4 complexes: hard anions as proton carriers

MY Darensbourg, MM Ludvig

Index: Darensbourg, Marcetta Y.; Ludvig, Maria M. Inorganic Chemistry, 1986 , vol. 25, p. 2894 - 2898

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Citation Number: 27

Abstract

Reported are kinetic studies of the deprotonation of [HMo (CO),(~),] BF, complexes (0= 1, 2- bis (diphenylphosphino) ethane, dppe; P'P= 1, 2-bis (dimethylphosphino) ethane, dmpe; P'P= 1, 2-bis (diethylphosphino) ethane, depe). Amine bases deprotonated the metalloacids slowly, ti,, typically being days, following the rate expression rate= k2 [MoH+][amine]. Deprotonation rates were dependent on the size of the amine bases and were greatly ...

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