Synthesis of peri-substituted naphthalenes and tetralins

N Pourahmady, EH Vickery…

Index: Pourahmady, Naser; Vickery, Euin H.; Eisenbraun, Edmund J. Journal of Organic Chemistry, 1982 , vol. 47, # 13 p. 2590 - 2593

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Citation Number: 11

Abstract

Unlike the other disubstituted naphthalene derivatives, peri-substituted naphthalenes cannot be synthesized by Friedel-Crafts condensation. Duswalt and Mayer3” prepared 13 of the 14 possible ethylmethylnaphthalenes by alkylating 1-and 2-methylnaphthalene. Sterically hindered 1-ethyl-8-methylnaphthalene was not found among the products. We did not anticipate that the preparation of 7 and 12 should present unusual synthesis problems ...

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