The Heck-type arylation of allylic alcohols with arenediazonium salts

J Masllorens, S Bouquillon, A Roglans, F Hénin…

Index: Masllorens, Judit; Bouquillon, Sandrine; Roglans, Anna; Henin, Francoise; Muzart, Jacques Journal of Organometallic Chemistry, 2005 , vol. 690, # 16 p. 3822 - 3826

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Citation Number: 47

Abstract

The Heck coupling of ArN 2 BF 4 with secondary allylic alcohols, carried out in methanol using Pd(dba) 2 as catalyst without extra ligands and base, leads to the corresponding β-arylated carbonyl compounds. Such conditions afford arylated acetals from primary allylic alcohols. ... The Heck coupling of ArN 2 BF 4 with allylic alcohols has been carried out in methanol using Pd(dba) 2 as catalyst in the absence of extra ligand and base. ... Some of us have recently reported ...

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