Catalysis letters

Nickel-catalyzed C (sp2)–C (sp2) Cross Coupling Reactions of Sulfur-Functionalities and Grignard Reagents

CI Someya, M Weidauer, S Enthaler

Index: Someya, Chika I.; Weidauer, Maik; Enthaler, Stephan Catalysis Letters, 2013 , vol. 143, # 5 p. 424 - 431

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Citation Number: 14

Abstract

Abstract In the present study, the nickel-catalyzed carbon carbon bond formation of a range of sulfur containing substrates with Grignard reagents via desulfurization has been explored. After investigation of different reaction parameters with a well-defined nickel complex an excellent and easy-accessible pre-catalyst was found. The obtained system was capable to convert a broad scope of substrates under mild reaction conditions. Graphical Abstract

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