Tetrahedron

Synthesis of trimethylsilyloxy and hydroxy compounds from carbanions and bis (trimethylsilyl) peroxide

L Camici, P Dembech, A Ricci, G Seconi, M Taddei

Index: Camici, Lucia; Dembech, Pasquale; Ricci, Alfredo; Seconi, Giancarlo; Taddei, Maurizio Tetrahedron, 1988 , vol. 44, # 13 p. 4197 - 4206

Full Text: HTML

Citation Number: 48

Abstract

The reactions of bis (trimethylsilyl) peroxide with alkyl, vinyl, alkynyl, aromatic and heteroaromatic anions are described. Depending on the reaction conditions, the trimethylsilyloxy derivatives can be obtained alone or together with the corresponding trimethylsilyl derivatives, which is sometimes the major product. Enolates, generated using magnesium diisopropylamide give the corresponding hydroxycarbonyl compounds in ...

Related Articles:

Simple and efficient MW-assisted cleavage of acetals and ketals in pure water

[Procopio, Antonio; Gaspari, Marco; Nardi, Monica; Oliverio, Manuela; Tagarelli, Antonio; Sindona, Giovanni Tetrahedron Letters, 2007 , vol. 48, # 49 p. 8623 - 8627]

Oxidation of ketone by palladium (II). α-Hydroxyketone synthesis catalyzed by a bimetallic palladium (II) complex

[El-Qisairi, Arab K; Qaseer, Hanan A Journal of Organometallic Chemistry, 2002 , vol. 659, # 1-2 p. 50 - 55]

Aerobic Oxidation of Vicinal Diols Catalyzed by an Anderson??Type Polyoxometalate,[IMo6O24] 5–

[Advanced Synthesis and Catalysis, , vol. 344, # 9 p. 1017 - 1021]

Aerobic Oxidation of Vicinal Diols Catalyzed by an Anderson??Type Polyoxometalate,[IMo6O24] 5–

[Advanced Synthesis and Catalysis, , vol. 344, # 9 p. 1017 - 1021]

Aqueous-phase hydrodeoxygenation of bio-derived phenols to cycloalkanes

[Journal of Catalysis, , vol. 280, # 1 p. 8 - 16]

More Articles...