Reactions of acylarylnitrosamines—II

P Miles, H Suschitzky

Index: Miles,P.; Suschitzky,H. Tetrahedron, 1962 , vol. 18, p. 1369 - 1376

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Citation Number: 9

Abstract

Decomposition of acylarylnitrosamines in benzene produces not only free radicals as is well recognized, but also intermediate ion pairs. The generality of this dual mechanism is experimentally demonstrated by use of nucleophilically activated fluorine as a 'label'. The appearance of acylfluoride in the reaction products from fluorine substituted acylarylnitrosamines is interpreted.