Organometallics

Catalytic Hydroalkylation of Olefins by Stabilized Carbon Nucleophiles Promoted by Dicationic Platinum (II) and Palladium (II) Complexes

ME Cucciolito, A D'Amora, A Vitagliano

Index: Cucciolito, Maria E.; Damora, Angela; Vitagliano, Aldo Organometallics, 2010 , vol. 29, # 22 p. 5878 - 5884

Full Text: HTML

Citation Number: 13

Abstract

The coordinated olefin in dicationic Pt2+ and Pd2+ complexes reacts with β-dicarbonyl compounds. In the presence of a base, stable metal− alkyl derivatives are obtained; otherwise a catalytic hydroalkylation reaction is obtained, whose rate-determining step is the protolytic cleavage of the metal− carbon bond.

Related Articles:

Metal triflate-catalyzed cationic benzylation and allylation of 1, 3-dicarbonyl compounds

[Arumugam, Subramaniam; McLeod, Dale; Verkade, John G. Journal of Organic Chemistry, 1998 , vol. 63, # 11 p. 3677 - 3679]

Dual formation of. beta.-diketones from methylene ketones and acetic anhydride by means of boron trifluoride. Improved method of synthesis of certain. beta.- …

[Mao,C.-L. et al. Journal of Organic Chemistry, 1969 , vol. 34, # 5 p. 1425 - 1429]

Synthesis of naturally occurring curcuminoids and related compounds

[Pedersen, Uffe; Rasmussen, Preben B.; Lawesson, Sven-Olov Liebigs Annalen der Chemie, 1985 , # 8 p. 1557 - 1569]

The Reaction of Oxymercurials with Active Methylene Compounds and the Demercuration of the Resulting Mercurials with Acid and Base

[Ichikawa,K. et al. Journal of Organic Chemistry, 1966 , vol. 31, p. 447 - 452]

Electroorganic chemistry. 103. Selective C-alkylation of. beta.-diketones

[Shono, Tatsuya; Kashimura, Shigenori; Sawamura, Masaya; Soejima, Takeshi Journal of Organic Chemistry, 1988 , vol. 53, # 4 p. 907 - 910]

More Articles...