Sulfite formation versus chlorination of benzyl alcohols with thionyl chloride

DA Rodriguez, R Priefer

Index: Rodriguez, Deana A.; Priefer, Ronny Tetrahedron Letters, 2014 , vol. 55, # 19 p. 3045 - 3048

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Abstract

Abstract Recently, we have reported the photolytic decay of a library of para-substituted dibenzylic sulfites in a Srinivasan–Griffin–Rayonet photochemical reactor. In an attempt to synthesize the complete library for that study we discovered that bis (p-methoxybenzyl) sulfite and bis (p-phenoxybenzyl) sulfite could not be formed and only their corresponding benzyl chlorides were synthesized. Thus, sulfite formation versus chlorination of a range ...