… complexes. 1. Complete assignment of the proton NMR spectra by two dimensional and NOE techniques. The nature of inside and outside proton chemical shift …

GS Rodman, KR Mann

Index: Rodman, Gary S.; Mann, Kent R. Inorganic Chemistry, 1988 , vol. 27, p. 3338 - 3346

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Citation Number: 46

Abstract

Six new d8-d8 complexes,[Ir (COD)(r-hp)],,[Ir (COD)(r-mhp) l,,[Ir (COD)(r-chp)],,[Ir (COD)(r- Zhq)],,[Rh (COD)(p-hp)],, and [Rh (COD)(g-mhp)],(hp= 2-hydroxypyridinate, mhp= 6-methyl-2- hydroxypyridinate, chp= 6-chloro-2-hydroxypyridinate, 2hq= 2-hydroxyquinolate, COD= 1, 5- cyclooctadiene), were synthesized and characterized by 'H NMR, I3C NMR, and IR spectroscopy and FAB mass spectrometry. Other than our preliminary communication, ...