Migratory insertion reactions of organometallics. 3. Carbon-carbon bond forming reactions of organotransition metals with. alpha.-or. gamma.-haloorganolithium …

…, K Akiyoshi, B O'Connor, K Takagi, G Wu

Index: Negishi, Ei-ichi; Akiyoshi, Kazunari; O'Connor, Brian; Takagi, Kentaro; Wu, Guangzhong Journal of the American Chemical Society, 1989 , vol. 111, # 8 p. 3089 - 3091

Full Text: HTML

Citation Number: 76

Abstract

We have recently reported9 that organometals containing various main group metals, such as AI, Mg, Zn, and Cd, react with LiCH (CI) SiMe2Ph5 to undergo CC bond formation, some of which have been shown to proceed via migratory insertion. In view of these favorable results, we reacted a wide variety of organotransition metals with 1 and 2 and indeed observed the desired CC bond formation according to the general equation shown below ...

Related Articles:

Palladium-catalysed preparation of 1, 2-dienes by selective hydrogenolysis of alk-2-ynyl carbonates with ammonium formate

[Tsuji, Jiro; Sugiura, Teruo; Yuhara, Masami; Minami, Ichiro Journal of the Chemical Society, Chemical Communications, 1986 , # 12 p. 922 - 924]

A suite of novel allenes from Australian melolonthine scarab beetles. Structure, synthesis, and stereochemistry

[McGrath, Matthew J.; Fletcher, Mary T.; Koenig, Wilfried A.; Moore, Christopher J.; Cribb, Bronwen W.; Allsopp, Peter G.; Kitching, William Journal of Organic Chemistry, 2003 , vol. 68, # 10 p. 3739 - 3748]

Anwendungen der Phasentransfer??katalyse, 14. Darstellung von Alkinen aus Alkylhalogeniden mit festem Kalium??tert??butylat und Kronenether

[Dehmlow, Eckehard V.; Lissel, Manfred Liebigs Annalen der Chemie, 1980 , # 1 p. 1 - 13]

Anwendungen der Phasentransfer??katalyse, 14. Darstellung von Alkinen aus Alkylhalogeniden mit festem Kalium??tert??butylat und Kronenether

[Dehmlow, Eckehard V.; Lissel, Manfred Liebigs Annalen der Chemie, 1980 , # 1 p. 1 - 13]

The Formation of Allenes from gem-Dihalocyclopropanes by Reaction with Alkyllithium Reagents1, 2

[Moore,W.R.; Ward,H.R. Journal of Organic Chemistry, 1962 , vol. 27, p. 4179 - 4181]

More Articles...