Journal of the American Chemical Society

The Base-catalyzed Reaction of Dialkyl Phosphonates with Isocyanates1

RB Fox, DL Venezky

Index: Fox; Venezky Journal of the American Chemical Society, 1956 , vol. 78, p. 1661

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Citation Number: 22

Abstract

In recent years, the addition of dialkyl phosphonates to unsaturated groupings such as carbonyl, imine or to activated carbon-carbon unsaturation has been extensively investigated. 2 These reactions are generally catalyzed by alkali metals or their alkoxides. Catalysis by other bases has not been rep~ rted.~ It has been assumed that the mechanism of these reactions involves the polarization of the unsaturated group by the metal salt of ...