Bicyclic Guanidine??Catalyzed Direct Asymmetric Allylic Addition of N??Aryl Alkylidene??Succinimides

J Wang, H Liu, Y Fan, Y Yang, Z Jiang…

Index: Wang, Jianmin; Liu, Hongjun; Fan, Yitian; Yang, Yuanyong; Jiang, Zhiyong; Tan, Choon-Hong Chemistry - A European Journal, 2010 , vol. 16, # 42 p. 12534 - 12537

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Abstract

The enantioselective functionalization of allylic positions has attracted the attention of organic chemists owing to the broad synthetic potential of the product, functionalized enantio- enriched alkenes.[1] Transition-metal-catalyzed asymmetric allylic alkylation is the most developed strategy in allylic transformations and its popularity is due to its tolerance to a variety of functional groups and its flexibility in diverse bond constructions.[2] However, the ...