Stabilization of 1, 3-dipoles by. pi.-complex formation. Iron carbonyl derivatives of thio-and selenoketocarbenes

GN Schrauzer, H Kisch

Index: Schrauzer; Kisch Journal of the American Chemical Society, 1973 , vol. 95, p. 2501,2503,2504,2507

Full Text: HTML

Citation Number: 49

Abstract

Abstract: Trihapto-1, 2-diphenylthioketocarbenehexacarbonyldiiron, the first transition metal derivative of a 1, 3-dipolar species, was obtained by the reaction of 1, 4-dimethylnickel (II) bis (cis-stilbenedithiolate) or of diphenyl-I, 2, 3-thiadiazole with iron carbonyls on heating and light irradiation. The corresponding selenoketocarbene complex was prepared analogously from diphenyl-l, 2, 3-selenodiazole. The same method was used to ...

Related Articles:

A study of Cu/ZnO/Al 2 O 3 methanol catalysts prepared by flame combustion synthesis

[Jensen; Johannessen; Wedel; Livbjerg Journal of Catalysis, 2003 , vol. 218, # 1 p. 67 - 77]

tmeda-Nickel-Komplexe: I.(tmeda) Ni (η2-C4H6) 2 und {(tmeda) Ni (η2C4H6)} 2 (η2, η2-C4H6)

[Schroeder, Wolfgang; Poerschke, Klaus R. Journal of Organometallic Chemistry, 1987 , vol. 322, p. 385 - 392]

Übergangsmetallkomplexe, I. Olefin??Komplexe des Nickels (0)

[Bogdanovic,B. et al. Justus Liebigs Annalen der Chemie, 1966 , vol. 699, p. 1 - 23]

Intramolecular rearrangement of the imine–amide ligand within the nickel coordination sphere affected by carbon monoxide

[Kraikivskii, Peter B.; Klein, Hans-Friedrich; Saraev, Vitaly V.; Schloerer, Nils E.; Bocharova, Victoria V. Journal of Organometallic Chemistry, 2011 , vol. 696, # 21 p. 3376 - 3383]

More Articles...