Synthetic communications

Efficient Synthesis of β??Alkyl/Arylsulfanyl Carbonyl Compounds by In??TMSCl??Promoted Cleavage of Dialkyl/Diaryl Disulfides and Subsequent Michael Addition

BC Ranu, T Mandal

Index: Ranu, Brindaban C.; Mandal, Tanmay Synthetic Communications, 2007 , vol. 37, # 9 p. 1517 - 1523

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Citation Number: 11

Abstract

Abstract A convenient and efficient procedure for the synthesis of β??alkyl/arylsulfanyl carbonyl compounds has been developed by a simple one??pot reaction of dialkyl/diaryl sulfides with α, β??unsaturated aldehydes, ketones, carboxylic esters, and nitriles in presence of indium and trimethylsilyl chloride under sonication.

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