p-Anisoyl chloride

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Names

[ CAS No. ]:
100-07-2

[ Name ]:
p-Anisoyl chloride

[Synonym ]:
p-Methoxybenzoyl chloride
p-Anisoyl chloride
p-methoxybenzoic chloride
4-Anisoyl chloride
EINECS 202-816-4
Benzoyl chloride,4-methoxy
para-methoxybenzoyl chloride
4-Methoxybenzoylchloride
4-Methoxybenzoic acid chloride
m-methylbenzoyl chloride
Anisoyl chloride
4-methoxyphenylcarbonyl chloride
Benzoyl chloride,p-methoxy
MFCD00000687
4-Methoxybenzoyl chloride
Benzoyl chloride, 4-methoxy-

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
263.2±13.0 °C at 760 mmHg

[ Melting Point ]:
22 °C(lit.)

[ Molecular Formula ]:
C8H7ClO2

[ Molecular Weight ]:
170.593

[ Flash Point ]:
87.8±0.0 °C

[ Exact Mass ]:
170.013458

[ PSA ]:
26.30000

[ LogP ]:
2.38

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.530

[ Stability ]:
Stable, but reacts violently with water. Ensure no moisture enters the container in which this material is stored, to prevent pressure build-up. Incompatible with water, moisture, strong bases, strong oxidizing agents.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45-S62

[ RIDADR ]:
UN 1729 8/PG 2

[ WGK Germany ]:
1

[ RTECS ]:
CA0270000

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2918990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • p-Anisic acid
  • carbon monoxide
  • 4-Iodoanisole
  • N,N-Dimethylformamide
  • 2-Methoxybenzoic acid
  • Oxalyl chloride
  • 4-Hydroxybenzoic acid
  • 1-((2R,4S,5S)-5-azido-4-hydroxy-5-(iodomethyl)tetrahydrofuran-2-yl)-5-methylpyrimidine-2,4(1H,3H)-dione
  • Methyl anisate
  • potassium,4-hydroxybenzoate

DownStream

  • imidazol-1-yl-(4-methoxyphenyl)methanone
  • Phosphonic acid,P-(4-methoxybenzoyl)-, dimethyl ester
  • (4-METHOXYPHENYL)(2-PHENYL-1H-INDOL-3-YL)METHANONE
  • [(4-methoxybenzoyl)amino] N,N-diethylcarbamodithioate
  • 5-(4-methoxyphenyl)-2,4-dimethyl-1,2,4-triazole-3-thione
  • 4-Methoxy-N-(2-methoxy-4-nitrophenyl)benzamide
  • 4-methoxy-N-(5-methyl-1,2-oxazol-3-yl)benzamide
  • 5-(4-methoxyphenyl)-1,3-diphenyl-1,2,4-triazole
  • propynyl 4-methoxybenzoate
  • 2-(4-methoxybenzoyl)-1,1-dioxo-1,2-benzothiazol-3-one

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

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Drug Des. Devel. Ther. 6 , 323-39, (2012)

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Related Compounds

  • p-anisoyl chloride
  • P-ANISOYL CHLORIDE
  • 3-iodo-p-anisoyl chloride
  • 2-Fluoro-p-anisoyl chloride
  • 3-Fluoro-p-anisoyl chloride
  • 2-(CYANOMETHYL)-P-ANISOYL CHLORIDE
  • 2-(6-Methoxy-1-naphthalenyl)piperidine
  • 4-(4-bromo-1-ethyl-1H-pyrazol-3-yl)pyridine
  • 5-[[6-Chloro-5-(2-phenylethynyl)-3H-imidazo[4,5-b]pyridin-2-yl]oxy]-2-methylbenzoic acid
  • 1-(4-bromophenyl)-1H-pyrazol-4-yl-2-methylpropan-2-ol
  • 4-Chloro-6-(4-cyclopropylpiperazin-1-yl)pyrimidine
  • Ethyl 3-(1-(methylamino)ethyl)-1h-1,2,4-triazole-5-carboxylate
  • 3-Amino-1-(3,4-dimethylphenyl)-4-(4-(trifluoromethyl)phenyl)azetidin-2-one
  • 2-Amino-4,4-dimethoxy-2-methylbutanenitrile
  • 1-(1-Methylpiperidin-4-yl)-N-(thiazol-4-ylmethyl)methanamine
  • 3-Cyclohexyl-3-hydroxybutanal