N-Methyl-4-nitroaniline

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Names

[ CAS No. ]:
100-15-2

[ Name ]:
N-Methyl-4-nitroaniline

[Synonym ]:
Aniline,N-methyl-p-nitro
N-Methyl-p-nitraniline
4-NO2-PhNHMe
Benzenamine,N-methyl-4-nitro
p-Nitro-N-methylaniline
4-methylaminonitrobenzene
Benzenamine, N-methyl-4-nitro-
EINECS 202-823-2
N-METHYL-4-NITROBENZENAMINE
N-methyl-4-nitro-aniline
MFCD00007305
4-Nitro-N-methylaniline
N-Monomethyl-p-nitroaniline
N-Methyl-4-nitroaniline
N-Methyl-p-nitroaniline

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
290.6±23.0 °C at 760 mmHg

[ Melting Point ]:
149-151 °C(lit.)

[ Molecular Formula ]:
C7H8N2O2

[ Molecular Weight ]:
152.151

[ Flash Point ]:
129.5±22.6 °C

[ Exact Mass ]:
152.058578

[ PSA ]:
57.85000

[ LogP ]:
2.04

[ Vapour density ]:
5.25 (vs air)

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.620

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
<0.1 g/100 mL at 19 ºC

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H373

[ Precautionary Statements ]:
P261-P280-P301 + P310-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R23/24/25;R36/37/38

[ Safety Phrases ]:
S28-S36/37/39-S45-S26

[ RIDADR ]:
2811

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2921430090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-Chloronitrobenzene
  • methylamine
  • 1H-BENZOTRIAZOLE-1-METHANOL
  • 4-Nitroaniline
  • Methylamine Acetate
  • 1-Bromo-4-nitrobenzene
  • 2-(methyl(4-nitrophenyl)amino)benzo[cd]indazol-3(2H)-one
  • N-methyl-N-nosyl-p-nitroaniline
  • Mercaptoacetic acid
  • N-Methylaniline

DownStream

  • pnb
  • Acetamide,N-methyl-N-(4-nitrophenyl)-2-phenoxy-
  • N-(2,4-dinitrophenyl)-N-methylnitramide
  • 2-Chloro-N-methyl-N-(4-nitrophenyl)acetamide
  • Nintedanib (BIBF 1120)
  • ethyl 1-methyl-5-nitro-3-phenylindole-2-carboxylate
  • Acetamide,N-methyl-N-(4-nitrophenyl)-
  • N-Methyl-N-(4-nitrophenyl)methanesulfonamide
  • N-methyl-4-nitro-N-(4-nitrophenyl)benzamide
  • N-Methyl-1,4-benzenediamine

Customs

[ HS Code ]: 2921430090

[ Summary ]:
HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Physicochemical properties of an insensitive munitions compound, N-methyl-4-nitroaniline (MNA).

J. Hazard. Mater. 155(1-2) , 288-94, (2008)

Accurate information on physicochemical properties of an organic contaminant is essential for predicting its environmental impact and fate. These properties also provide invaluable information for the...

Continuous treatment of the insensitive munitions compound N-methyl-p-nitro aniline (MNA) in an upflow anaerobic sludge blanket (UASB) bioreactor.

Chemosphere 144 , 1116-22, (2015)

N-methyl-p-nitroaniline (MNA) is an ingredient of insensitive munitions (IM) compounds that serves as a plasticizer and helps reduce unwanted detonations. As its use becomes widespread, MNA waste stre...

Aerobic degradation of N-methyl-4-nitroaniline (MNA) by Pseudomonas sp. strain FK357 isolated from soil.

PLoS ONE 8 , e75046, (2013)

N-Methyl-4-nitroaniline (MNA) is used as an additive to lower the melting temperature of energetic materials in the synthesis of insensitive explosives. Although the biotransformation of MNA under ana...


More Articles

Related Compounds

  • N-BOC-N-methyl-4-nitroaniline
  • 2-Bromo-N-methyl-4-nitroaniline
  • N-ethyl-N-methyl-4-nitroaniline
  • N-butyl-N-methyl-4-nitroaniline
  • 2-Fluoro-N-methyl-4-nitroaniline
  • 3-chloro-N-methyl-4-nitroaniline
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • Glucopyranose, 3-(2,4,6-trimethylbenzoate), I(2)-D-
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide