Benzyl bromide

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Names

[ CAS No. ]:
100-39-0

[ Name ]:
Benzyl bromide

[Synonym ]:
α-bromo toluene
Benzybromide
α-BROMOTOLUENE
Benzene, (bromomethyl)-
EINECS 202-847-3
benzylbromide
Bromo Thluene
A-BROMOTOLUENE
1-Bromotoluene
cyclite
MFCD00000172
(bromomethyl)-benzene
Benzyl bromide
phenylmethyl bromide
(Bromomethyl)benzene

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
198.5±0.0 °C at 760 mmHg

[ Melting Point ]:
-3 °C

[ Molecular Formula ]:
C₇H₇Br

[ Molecular Weight ]:
171.035

[ Flash Point ]:
86.7±0.0 °C

[ Exact Mass ]:
169.973099

[ LogP ]:
2.92

[ Vapour density ]:
5.8 (vs air)

[ Vapour Pressure ]:
0.5±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.568

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XS7965000

CHEMICAL NAME :: Toluene, alpha-bromo-

CAS REGISTRY NUMBER :: 100-39-0

LAST UPDATED :: 199707

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C7-H7-Br

MOLECULAR WEIGHT :: 171.05

WISWESSER LINE NOTATION :: E1R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Rodent - hamster Ovary

DOSE/DURATION :: 30 umol/L

REFERENCE :: JJATDK JAT, Journal of Applied Toxicology. (John Wiley & Sons Ltd., Baffins Lane, Chichester, W. Sussex PO19 1UD, UK) V.1- 1981- Volume(issue)/page/year: 3,203,1983

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S39-S2

[ RIDADR ]:
UN 1737 6.1/PG 2

[ WGK Germany ]:
2

[ RTECS ]:
XS7965000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
2827590000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Benzyl alcohol
Ammonium acetate
Toluene
2-(benzylthio)-5-methoxy-1,3-dimethyl-1H-benzo[d]imidazol-3-ium trifluoromethanesulfonate
Benzaldehyde
phenetole
Benzyl methanesulfonate
4,4,5,5-Tetramethyl-2-(p-tolyl)-1,3,2-dioxaborolane
2-BENZYLOXYTETRAHYDROPYRAN
Benzyl chloride

DownStream

1-BENZYL-3,4-DIHYDRO-1H-PYRIDIN-2-ONE
7-(benzyloxy)-5-hydroxy-2-phenyl-4H-chromen-4-one
ethyl 3-(benzyloxy)cyclobutanecarboxylate
6-benzyl-2-methylpyridine
1H-Imidazole-2-carboxaldehyde,1-(phenylmethyl)-
1-phenylmethoxy-4-(2,4,4-trimethylpentan-2-yl)benzene
2-Benzyl-4-(1,1,3,3-tetramethyl-butyl)-phenol
3,4-dimethyl-3,4-diphenylhexane
(2-methyl-1-phenylbutan-2-yl)benzene
(1Z)-1-(5-benzylsulfanyltriazol-4-ylidene)-N',N'-dimethylmethanediamine,hydrochloride

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

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