Benzylamine

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Names

[ CAS No. ]:
100-46-9

[ Name ]:
Benzylamine

[Synonym ]:
aminomethylbenzene
Phenylmethanamine
MFCD00212756
1-Phenylmethanamine
phenylmethanaminium
BENZYLAMIN, (ACIDIMETRISCH)
PHENYL-METHANAMINE
ω-Aminotoluene
benzyl amine
phenylmethylamine
BENZYLAMINE (100 ML )
α-Aminotoluene
Benzylamin
BENZYLAMINE FOR SYNTHESIS
EINECS 202-854-1
N-benzylamine
Benzenemethanamine
w-Aminotoluene
p-Aminomethylbenzene
Benzylamine
a-Aminotoluene

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
185.0±0.0 °C at 760 mmHg

[ Melting Point ]:
-30 °C

[ Molecular Formula ]:
C₇H₉N

[ Molecular Weight ]:
107.153

[ Flash Point ]:
60.0±0.0 °C

[ Exact Mass ]:
107.073502

[ PSA ]:
26.02000

[ LogP ]:
1.09

[ Vapour Pressure ]:
0.7±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.547

[ Stability ]:
Stability Combustible. Incompatible with strong oxidizing agents, strong acids.

[ Water Solubility ]:
soluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DP1488500

CHEMICAL NAME :: Benzylamine

CAS REGISTRY NUMBER :: 100-46-9

BEILSTEIN REFERENCE NO. :: 0741984

LAST UPDATED :: 199710

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C7-H9-N

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: USXXAM United States Patent Document. (U.S. Patent Office, Box 9, Washington, DC 20231) Volume(issue)/page/year: #3816470

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 700 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 39(4),86,1974 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M2937 No. of Facilities: 369 (estimated) No. of Industries: 7 No. of Occupations: 7 No. of Employees: 932 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M2937 No. of Facilities: 87 (estimated) No. of Industries: 3 No. of Occupations: 7 No. of Employees: 5721 (estimated) No. of Female Employees: 844 (estimated)

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302 + H312-H314

[ Precautionary Statements ]:
P301 + P312 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R21/22;R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 2735 8/PG 2

[ WGK Germany ]:
1

[ RTECS ]:
DP1488500

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2921499090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

BTS
4-Fluorobenzaldehyde
Benzonitrile
benzyl azide
Benzenemethanamine,N-2-propyn-1-yl-
n-benzylacetamide
Benzyl alcohol
Benzamide, N-(phenylmethyl)-
Benzaldoxime
N-Boc benzylamine

DownStream

1-BENZYL-3,4-DIHYDRO-1H-PYRIDIN-2-ONE
N-benzyl-3-chloro-2-trimethylsilyloxypropan-1-amine
N,N''-DIBENZYL-MALONAMIDE
2,4,6-Trichlorophenol
ethyl (N-benzylcarbamoyl)acetate
1-benzyl-2-(trifluoromethyl)aziridine
3-(2-nitrovinyl)thiophene
N-Benzyl-(3S)-hydroxysuccinimide
5-chloro-2-phenyl-1,3-benzoxazole
6-methoxy-2-phenyl-1,3-benzothiazole

Customs

[ HS Code ]: 2921499090

[ Summary ]:
2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Calculating virtual log P in the alkane/water system (log P(N)(alk)) and its derived parameters deltalog P(N)(oct-alk) and log D(pH)(alk).

J. Med. Chem. 48 , 3269-79, (2005)

Growing interest in the use of both the logarithm of the partition coefficient of the neutral species in the alkane/water system (log P(N)(alk)) and the difference between log P(N)(oct) (the logarithm...

Determination of human serum semicarbazide-sensitive amine oxidase activity via flow injection analysis with fluorescence detection after online derivatization of the enzymatically produced benzaldehyde with 1,2-diaminoanthraquinone.

Anal. Chim. Acta 881 , 139-47, (2015)

A fast, simple, and sensitive flow injection analysis method was developed for the measurement of semicarbazide-sensitive amine oxidase (SSAO) activity in human serum. Benzaldehyde, generated by the a...

Vascular adhesion protein-1 promotes liver inflammation and drives hepatic fibrosis.

J. Clin. Invest. 125(2) , 501-20, (2015)

Nonalcoholic fatty liver disease (NAFLD) encompasses a range of manifestations, including steatosis and cirrhosis. Progressive disease is characterized by hepatic leukocyte accumulation in the form of...