Disulfur dichloride

Names

[ CAS No. ]:
10025-67-9

[ Name ]:
Disulfur dichloride

[Synonym ]:
MFCD00011446
Disulfur dichloride
chlorosulfanyl thiohypochlorite
EINECS 233-036-2

Chemical & Physical Properties

[ Density]:
1.688 g/mL at 25 °C(lit.)

[ Boiling Point ]:
138 °C(lit.)

[ Melting Point ]:
−80 °C(lit.)

[ Molecular Formula ]:
Cl₂S₂

[ Molecular Weight ]:
135.03600

[ Flash Point ]:
118ºC

[ Exact Mass ]:
133.88200

[ PSA ]:
50.60000

[ LogP ]:
2.67540

[ Vapour density ]:
4.7 (vs air)

[ Vapour Pressure ]:
6.8 mm Hg ( 20 °C)

[ Index of Refraction ]:
n20/D 1.658(lit.)

[ Water Solubility ]:
reacts

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: WS4300000

CHEMICAL NAME :: Sulfur chloride

CAS REGISTRY NUMBER :: 10025-67-9

LAST UPDATED :: 199712

DATA ITEMS CITED :: 25

MOLECULAR FORMULA :: Cl2-S2

MOLECULAR WEIGHT :: 135.02

WISWESSER LINE NOTATION :: S2 G2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 150 ppm

REFERENCE :: IPSTB3 International Polymer Science and Technology. (Rapra Technology Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year: 3,93,1976 *** REVIEWS *** ACGIH TLV-CL 5.5 mg/m3 (1 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** OSHA PEL (Gen Indu):8H TWA 1 ppm (6 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 ppm (6 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 ppm (6 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 ppm (6 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 1 ppm (6 mg/m3) JAN 1993 OEL-BELGIUM:STEL 1 ppm (5.5 mg/m3) JAN 1993 OEL-DENMARK:TWA 1 ppm (6 mg/m3) JAN 1993 OEL-FINLAND:TWA 1 ppm (6 mg/m3);STEL 2 ppm (12 mg/m3);Skin JAN 1993 OEL-GERMANY:TWA 1 ppm (6 mg/m3) JAN 1993 OEL-HUNGARY:STEL 5 mg/m3 JAN 1993 OEL-JAPAN:STEL 1 ppm (5.5 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 1 ppm (6 mg/m3) JAN 1993 OEL-THE PHILIPPINES:TWA 6 mg/m3 JAN 1993 OEL-POLAND:TWA 5 mg/m3 JAN 1993 OEL-RUSSIA:STEL 1 ppm (0.3 mg/m3);Skin JAN 1993 OEL-SWITZERLAND:TWA 1 ppm (6 mg/m3);STEL 2 ppm (12 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 1 ppm (6 mg/m3);STEL 3 ppm (18 mg/m3) JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO SULFUR MONOCHLORIDE-air:CL 1 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5495 No. of Facilities: 964 (estimated) No. of Industries: 21 No. of Occupations: 28 No. of Employees: 28182 (estimated) No. of Female Employees: 2203 (estimated)

Safety Information

[ Symbol ]:

GHS05, GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H331-H314-H400

[ Supplemental HS ]:
Contact with water liberates toxic gas., Reacts violently with water.

[ Precautionary Statements ]:
P280-P301 + P310 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P403 + P233

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;C:Corrosive;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R14;R20;R25;R29;R35;R50

[ Safety Phrases ]:
S26-S36/37/39-S45-S61

[ RIDADR ]:
UN 3390 6.1/PG 1

[ WGK Germany ]:
3

[ RTECS ]:
WS4300000

[ Packaging Group ]:
I

[ Hazard Class ]:
8

[ HS Code ]:
2812104100

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Chlorine
Sulfur
Selenium oxydichloride
Carbon tetrachloride
Sulfuryl chloride
Thionyl chloride
Sulfur dichloride
tin
cyclooctasulfur

DownStream

Phosphorus thiochloride
Phosphorus pentachloride
SULFUR DIOXIDE
phosphoryl trichloride
Sulfur
Phosphorus trichloride
Bromine
cyclooctasulfur
hexathiane
cyclodecasulfur

Customs

[ HS Code ]: 2812104100

Articles

Synthesis of taurine analogues from alkenes: preparation of 2-aminocycloalkanesulfonic acids.

Adv. Exp. Med. Biol. 483 , 399-401, (2000)

(+/-)trans 2-Aminocyclohexanesulfonic acid and (+/-)trans 2-aminocyclopentanesulfonic acid were prepared from cyclohexene and cyclopentene respectively by sulfur monochloride addition, followed by oxi...

[Eye burn caused by sulfur monochloride].

Bull. Soc. Ophtalmol. Fr. 87(3) , 429-30, (1987)

Hypochlorite-induced oxidation of thiols: formation of thiyl radicals and the role of sulfenyl chlorides as intermediates.

Free Radic. Res. 33(6) , 719-29, (2000)

Activated phagocytic cells generate hypochlorite (HOCl) via release of hydrogen peroxide and the enzyme myeloperoxidase. HOCl plays an important role in bacterial cell killing, but excessive or mispla...

disulfur dihydroxide
disulfur(•1+)
disulfur bis{bis(trifluoromethyl)amide}
disulfur dinitride
disulfur dioxide
Disulfur monoxide
rac-(1R,2R,4S)-7-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3,3-dimethylbutanoyl]-7-azabicyclo[2.2.1]heptane-2-carboxylic acid
rac-tert-butyl (3R,4S)-3-hydroxy-4-[(1-methyl-1H-imidazol-2-yl)methyl]pyrrolidine-1-carboxylate
2-(4-Bromo-2,5-dimethylthiophen-3-yl)ethan-1-ol
3-iodo-1-methyl-5-propyl-1H-1,2,4-triazole
1-[2-(2-hydroxyethoxy)ethyl]-5-(3-methylbutyl)-1H-1,2,3-triazole-4-carboxamide
1-(3-hydroxy-2,2-dimethylpropyl)-5-(3-methylbutyl)-1H-1,2,3-triazole-4-carboxamide
1-(2-cyclobutylethyl)-5-(3-methylbutyl)-1H-1,2,3-triazole-4-carboxamide
Methyl 4-(piperidin-4-yl)pyrrolidine-3-carboxylate dihydrochloride
5-cyclobutyl-1-(2,2-difluoroethyl)-1H-1,2,3-triazole-4-carboxamide
5-(cyclopropylmethyl)-1-[3-(dimethylamino)propyl]-1H-1,2,3-triazole-4-carboxamide

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