2-Amino-5-formylthiazole

Names

[ CAS No. ]:
1003-61-8

[ Name ]:
2-Amino-5-formylthiazole

[Synonym ]:
2-amino-1,3-thiazole-5-carbaldehyde
2-Aminothiazole-5-carbaldehyde
MFCD02179570

Chemical & Physical Properties

[ Density]:
1.488g/cm3

[ Boiling Point ]:
316.3ºC at 760mmHg

[ Melting Point ]:
122-132 °C

[ Molecular Formula ]:
C₄H₄N₂OS

[ Molecular Weight ]:
128.15200

[ Flash Point ]:
145.1ºC

[ Exact Mass ]:
128.00400

[ PSA ]:
84.22000

[ LogP ]:
1.11900

[ Vapour Pressure ]:
0.000413mmHg at 25°C

[ Index of Refraction ]:
1.712

[ Storage condition ]:
Keep Cold

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H317-H319-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22;R36/37/38;R43

[ Safety Phrases ]:
S26-S36/37

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2934100090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-Bromomalonaldehyde
N,N-bis(trimethylsilyl)-2-aminothiazole
N,N-Dimethylformamide

DownStream

tert-Butyl (5-formyl-1,3-thiazol-2-yl)carbamate
2-(4-Methylpiperazino)-1,3-thiazole-5-carbaldehyde
2-Bromo-1,3-thiazole-5-carbaldehyde
2-Amino-5-thiazolemethanol
TERT-BUTYL 4-(6-((5-FORMYLTHIAZOL-2-YL)AMINO)-2-METHYLPYRIMIDIN-4-YL)PIPERAZINE-1-CARBOXYLATE

Customs

[ HS Code ]: 2934100090

[ Summary ]:
2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

Tetrahedron 64 , 299, (2008)

2-Amino-5-formylthiazole hydrochloride
2-amino-5-methoxy-4-phenylmethoxybenzamide
2-Amino-5-phenylnaphthalene
2-amino-5-(4-amino-3-cyanophenoxy)benzonitrile
2-amino-5,6-dihydro-4H-1,3-thiazin-4-one
2-Amino-5-chloropyridin-3-ol
2-Amino-5-cyclopropyl-1,4,5,6-tetrahydropyrimidine-4,6-dione
2-[(2S)-1-[(1RS,3SR)-3-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-2,2-difluorocyclopropanecarbonyl]pyrrolidin-2-yl]acetic acid
2-[(2S)-1-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-1-methyl-1H-pyrazole-4-carbonyl]pyrrolidin-2-yl]acetic acid
1-(8-tert-butyl-6-methoxy-2H-chromen-3-yl)ethan-1-one
2-[(2S)-1-[(3R)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)hexanoyl]pyrrolidin-2-yl]acetic acid
2-[(2R)-1-{2-[(1RS,3SR)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclopentyl]acetyl}pyrrolidin-2-yl]acetic acid
1-(8-bromo-3,4-dihydro-2H-1-benzopyran-3-yl)ethan-1-amine
2-[(2S)-1-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-methoxypropanoyl]pyrrolidin-2-yl]acetic acid
1-(6-fluoro-7-methoxy-3,4-dihydro-2H-1-benzopyran-3-yl)ethan-1-amine
methyl 3-[(1S)-1-aminoethyl]-3,4-dihydro-2H-1-benzopyran-6-carboxylate

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