Rhodium trichloride

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Names

[ CAS No. ]:
10049-07-7

[ Name ]:
Rhodium trichloride

[Synonym ]:
EINECS 233-165-4
MFCD00011204
rhodium chloride
Rhodium(III) chloride
Rhodium(3+) trichloride

Chemical & Physical Properties

[ Density]:
5.38

[ Boiling Point ]:
717ºC (730 mmHg)

[ Melting Point ]:
450ºC

[ Molecular Formula ]:
Cl3Rh

[ Molecular Weight ]:
209.264

[ Exact Mass ]:
207.812057

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
VI9275000
CAS REGISTRY NUMBER :
10049-07-7
LAST UPDATED :
199712
DATA ITEMS CITED :
33
MOLECULAR FORMULA :
Cl3-Rh
MOLECULAR WEIGHT :
209.26
WISWESSER LINE NOTATION :
RH G3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1302 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
280 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
198 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory depression Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
LD10 - Lethal Dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
879 mg/kg
TOXIC EFFECTS :
Tumorigenic - active as anti-cancer agent
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
215 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory depression Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
940 mg/kg/66W-C
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Lungs, Thorax, or Respiration - tumors Blood - leukemia
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intratesticular
DOSE :
16741 ug/kg
SEX/DURATION :
male 1 day(s) pre-mating
TOXIC EFFECTS :
Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Paternal Effects - testes, epididymis, sperm duct

MUTATION DATA

TYPE OF TEST :
DNA repair
TEST SYSTEM :
Bacteria - Bacillus subtilis
DOSE/DURATION :
5 mmol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 77,109,1980 *** REVIEWS *** ACGIH TLV-TWA 0.01 mg(Rh)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.1 mg(Rh)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,222,1971 OSHA PEL (Gen Indu):8H TWA 0.001 mg(Rh)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.001 mg(Rh)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.001 mg(Rh)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.001 mg(Rh)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 1 mg(Rh)/m3 JAN 1993 OEL-BELGIUM:TWA 1 mg(Rh)/m3 JAN 1993 OEL-DENMARK:TWA 0.001 mg(Rh)/m3 JAN 1993 OEL-DENMARK:TWA 0.1 mg(Rh)/m3 JAN 1993 OEL-FINLAND:TWA 0.001 mg(Rh)/m3;Skin JAN 1993 OEL-FINLAND:TWA 0.1 mg(Rh)/m3 JAN 1993 OEL-FRANCE:TWA 1 mg(Rh)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.001 mg(Rh)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg(Rh)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.1 mg(Rh)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.001 mg(Rh)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Rh)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.001 mg(Rh)/m3;STEL 0.003 mg(Rh)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.1 mg(Rh)/m3;STEL 0.3 mg(Rh)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22;R41

[ Safety Phrases ]:
S24-S26-S36/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
VI9275000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Chlorine
  • rhodium
  • Phosphorus trichloride
  • Phosphorus pentachloride
  • sodium chloride

DownStream

  • methyldiphenylphosphine oxide
  • CHLOROBIS(2-PHENYLPYRIDINE)RHODIUM(III)&
  • (1,5-Cyclooctadiene)rhodium chloride dimer
  • Rhodium trichloride
  • rhodium(3+),tribromide
  • Bis(pentafluorophenyl) perdisulfide
  • dichlororhodium; 1H-pyrazole
  • Chlorine
  • rhodium

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