2-Phenylpyridine

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Names

[ Name ]:
2-Phenylpyridine

[Synonym ]:
Pyridine,2-phenyl
p-di-pyridin-2-yl benzene
2-pyridylbenzene
MFCD00006280
2-phenyl pyridine
2-phenylpyridinate[H]
Pyridine, 2-phenyl-
o-Phenylpyridine
2-Azabiphenyl
EINECS 213-763-1
2-Phenylpyridine
phenylpyridine
azabiphenyl

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
270.8±9.0 °C at 760 mmHg

[ Melting Point ]:
-5°C

[ Molecular Formula ]:
C₁₁H₉N

[ Molecular Weight ]:
155.196

[ Flash Point ]:
113.3±11.4 °C

[ Exact Mass ]:
155.073502

[ PSA ]:
12.89000

[ LogP ]:
2.63

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.576

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UT7140900

CHEMICAL NAME :: Pyridine, 2-phenyl-

CAS REGISTRY NUMBER :: 1008-89-5

LAST UPDATED :: 199710

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C11-H9-N

MOLECULAR WEIGHT :: 155.21

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Sex chromosome loss and nondisjunction

TEST SYSTEM :: Yeast - Saccharomyces cerevisiae

DOSE/DURATION :: 250 ppm

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 163,23,1986

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
UT7140900

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-(Dimethylphenylsilyl)benzyl alcohol
2-Iodopyridine
2-Chloropyridine
Phenyltrimethoxysilane
Tri-n-butylphenyltin
2-Methoxypyridine
P-TOLYLMAGNESIUM BROMIDE
benzene
Phenylboronic acid
PHENYLMAGNESIUM CHLORIDE

DownStream

methyl 4-pyridin-2-ylbenzoate
METHYL 4-(3-PYRIDINYL)BENZOATE
METHYL 4-(PYRIDIN-4-YL)BENZOATE
2-(3-nitrophenyl)pyridine
5-Nitro-2-phenylpyridine
2-brom-6-phenylpyridin
2-Phenylpiperidine
2-Cyclohexylpiperidine
2-Amino-6-phenylpyridine
2,6-DIPHENYLPYRIDINE

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Synthesis, characterization, photophysics and electrochemical study of luminescent iridium(III) complexes with isocyanoborate ligands.

Dalton Trans. 44 , 15135-44, (2015)

A new series of cyclometalated iridium(III) complexes with isocyanoborate ligands [Ir(R2ppy)2(L)(CNBR'3)] (R = H or F; L = CNC6H4Cl-4 or PPh3; R' = Ph, C6F5 or C6H4Cl-4), [Ir(biqb)(ppy)(CNBR''3)] (R''...

Cyclometalated iridium(III) bipyridyl-phenylenediamine complexes with multicolor phosphorescence: synthesis, electrochemistry, photophysics, and intracellular nitric oxide sensing.

ChemMedChem 9(6) , 1316-29, (2014)

We present a new class of phosphorescent cyclometalated iridium(III) bipyridyl-phenylenediamine complexes [Ir(N^C)2 (bpy-DA)](PF6 ) (bpy-DA=4-(N-(2-amino-5-methoxyphenyl)aminomethyl)-4'-methyl-2,2'-bi...

Direct, catalytic, and regioselective synthesis of 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles from N-oxides.

Org. Lett. 16(3) , 864-7, (2014)

A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of cop...