Trimethylsilyl methanesulfonate

Names

[ Name ]:
Trimethylsilyl methanesulfonate

[Synonym ]:
Trimethylsilyl methanesulfonate
MFCD00042815
EINECS 233-220-2
Silanol, 1,1,1-trimethyl-, methanesulfonate
Silanol, trimethyl-, methanesulfonate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
209.8±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₄H₁₂O₃SSi

[ Molecular Weight ]:
168.287

[ Flash Point ]:
66.7±18.7 °C

[ Exact Mass ]:
168.027634

[ PSA ]:
51.75000

[ LogP ]:
1.01

[ Vapour Pressure ]:
0.3±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.420

MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F+

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
23-24/25

[ RIDADR ]:
UN 3272

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

A new catalyst for reductive cleavage of methylated glycans.

Carbohydr. Res. 163(2) , 247-61, (1987)

Several per-O-methylated D-glucans and D-fructans were used as models in an attempt to identify new catalysts for carrying out reductive cleavage. Included in these model studies were several D-glucan...

H.H. Hergott, G. Simchen

Liebigs Ann. Chem. , 1718, (1980)

methanesulfonic acid,6-methyl-7-trimethylsilylhept-5-en-2-ol
methanesulfonic acid,6-trimethylsilylhex-4-en-1-ol
(Trimethylsilyl)methyl acrylate
trimethylsilyl 8-aminooctanoate
trimethylsilyl 4-iodobutanoate
trimethylsilyl 2-phenylsulfanylacetate
2-Naphthalenecarboxamide, N,Na(2)-[1,1a(2)-biphenyl]-4,4a(2)-diylbis[4-[(4-chloro-2,5-dimethoxyphenyl)azo]-3-hydroxy-
1-[(1-Chloro-3-iodo-2-methylpropan-2-yl)oxy]-4-methylcyclohexane
3-(4-Methylphenyl)-1,2,4-oxadiazole-5-carboxylic acid 2-[[4-[(3-methylbenzoyl)oxy]phenyl]methylene]hydrazide
Pyrrolo[3,2-b]pyrrole-1(2H)-carboxylic acid, 3,6-difluorohexahydro-, 1,1-dimethylethyl ester, (3aR,6aR)-rel-
Ethyl 4-fluoro-2-nitro-5-[(propan-2-yl)amino]benzoate
(3I(2),12I(2))-20-(I+/--L-Arabinopyranosyloxy)-12-hydroxydammar-24-en-3-yl 2-O-I(2)-D-glucopyranosyl-I(2)-D-glucopyranoside
Benzoic acid, 4-[[[3-[[(phenylmethyl)amino]carbonyl]imidazo[1,5-a]pyridin-1-yl]carbonyl]amino]-, ethyl ester
3H,6H-5,11b-Ethano[1,3]dioxolo[4,5-j]phenanthridin-12-one, 4,4a-dihydro-3-methoxy-, oxime, (3S,4aS,5S,11bS)-
5H-Imidazo[1,5-a][1,4]diazepine-8(9H)-carboxylic acid, 6-(aminomethyl)-6,7-dihydro-, 1,1-dimethylethyl ester
1-cyclobutanecarbonyl-octahydro-1H-indol-3a-amine

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