Cloprop

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Names

[ CAS No. ]:
101-10-0

[ Name ]:
Cloprop

[Synonym ]:
2-(3-Chlorophenoxy)propionic Acid
MFCD00009723
Propanoic acid, 2-(3-chlorophenoxy)-
Cloprop
rac-(2R)-2-(3-chlorophenoxy)propanoic acid
DL-2-(m-Chlorophenoxy)Propionic Acid
2-(3-Chlorophenoxy)propanoic acid
2-(3-Chlorophenoxy)-propionic acid
(RS)-2-(3-chlorophenoxy)propionic acid
EINECS 202-915-2

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
318.5±17.0 °C at 760 mmHg

[ Melting Point ]:
113-115 °C(lit.)

[ Molecular Formula ]:
C9H9ClO3

[ Molecular Weight ]:
200.619

[ Flash Point ]:
146.4±20.9 °C

[ Exact Mass ]:
200.024017

[ PSA ]:
46.53000

[ LogP ]:
2.52

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.547

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UE9285000
CHEMICAL NAME :
Propionic acid, 2-(m-chlorophenoxy)-
CAS REGISTRY NUMBER :
101-10-0
BEILSTEIN REFERENCE NO. :
1876444
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C9-H9-Cl-O3
MOLECULAR WEIGHT :
200.63

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>750 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C147,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,180,1991 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ RTECS ]:
UE9285000

[ Hazard Class ]:
3.2

[ HS Code ]:
2918990028

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 3-Chlorophenol
  • 2-Chloropropanoic acid
  • 2-Bromopropionic Acid
  • m-chlorophenol, potassium salt
  • methyl 2-(3-chlorophenoxy)propionate
  • sodium 3-chlorophenoxide
  • Ethyl (2S)-2-bromopropanoate

DownStream

  • 3-Chlorophenol
  • carbon monoxide
  • ch3cho

Customs

[ HS Code ]: 2918990028

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