2,4,6-TRIS(ALLYLOXY)-S-TRIAZINE

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Names

[ CAS No. ]:
101-37-1

[ Name ]:
2,4,6-TRIS(ALLYLOXY)-S-TRIAZINE

[Synonym ]:
EINECS 202-936-7
2,4,6-Triallyloxy-1,3,5-triazine
Cyanuric Acid Triallyl Ester
2,4,6-Tris(allyloxy)-1,3,5-triazine
2,4,6-TRIS(ALLYLOXY)-S-TRIAZINE
2,4,6-tris(prop-2-enoxy)-1,3,5-triazine
MFCD00006049
1,3,5-Triazine, 2,4,6-tris(2-propen-1-yloxy)-
2,4,6-tris(prop-2-en-1-yloxy)-1,3,5-triazine

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
360.4±52.0 °C at 760 mmHg

[ Melting Point ]:
26-28 °C

[ Molecular Formula ]:
C12H15N3O3

[ Molecular Weight ]:
249.266

[ Flash Point ]:
131.5±20.9 °C

[ Exact Mass ]:
249.111343

[ PSA ]:
66.36000

[ LogP ]:
2.81

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.511

[ Stability ]:
Stable, but moisture-sensitive. Incompatible with acids, peroxides, strong oxidizing agents, copper, iron and its salts.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XZ2080000
CHEMICAL NAME :
s-Triazine, 2,4,6-tris(allyloxy)-
CAS REGISTRY NUMBER :
101-37-1
BEILSTEIN REFERENCE NO. :
0235560
LAST UPDATED :
199709
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C12-H15-N3-O3
MOLECULAR WEIGHT :
249.30
WISWESSER LINE NOTATION :
T6N CN ENJ BO2U1 DO2U1 FO2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
590 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation Behavioral - somnolence (general depressed activity) Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,42,1990
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>333 mg/m3/1H
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity)
REFERENCE :
ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,42,1990
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00905
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
8600 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity)
REFERENCE :
ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,42,1990 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83485 No. of Facilities: 21 (estimated) No. of Industries: 1 No. of Occupations: 6 No. of Employees: 171 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83485 No. of Facilities: 81 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 648 (estimated) No. of Female Employees: 345 (estimated)

Safety Information

[ Symbol ]:

GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H411

[ Precautionary Statements ]:
P273

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R51/53

[ Safety Phrases ]:
S36-S61

[ RIDADR ]:
UN 3077 9/PG 3

[ WGK Germany ]:
2

[ RTECS ]:
XZ2080000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
2933699090

Synthetic Route

Precursor & DownStream

Precursor

  • Cyanuric chloride
  • Allyl alcohol
  • sodium allyloxide

DownStream

  • Allyl ether
  • Diallyl isocyanurate
  • Triallyl isocyanurate
  • 1-prop-2-enyl-1,3,5-triazinane-2,4,6-trione
  • Allyl chloroacetate
  • Allyl acetate
  • 1-allyl-3,5-bis(2-methylallyl)-1,3,5-triazinane-2,4,6-trione
  • 1,3-diallyl-5-(2-methyl-allyl)-[1,3,5]triazinane-2,4,6-trione
  • TRIMETHALLYLISOCYANURATE
  • 2,4,6-tris(2,3-dibromopropoxy)-1,3,5-triazine

Customs

[ HS Code ]: 2933699090

[ Summary ]:
2933699090 other compounds containing an unfused triazine ring (whether or not hydrogenated) in the structure。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:20.0%

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Related Compounds

  • 2,4,6-tris(perfluorononyl)-s-triazine
  • 2,4,6-TRIS(P-BROMOPHENYL)-S-TRIAZINE
  • 2,4,6-TRIS(P-CHLOROPHENYL)-S-TRIAZINE
  • 2,4,6-tris(4-acetamidophenyl)-s-triazine
  • 2,4,6-tris(dichloromethyl)-1,3,5-triazine
  • 2,4,6-tris(3-methylphenoxy)-1,3,5-triazine