2-BENZYL-1,3-DIOXOLANE

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Names

[ CAS No. ]:
101-49-5

[ Name ]:
2-BENZYL-1,3-DIOXOLANE

[Synonym ]:
Phenylacetaldehyde Ethylene Acetal
MFCD00003215
2-BENZYL-1,3-DIOXOLANE
EINECS 202-946-1

Chemical & Physical Properties

[ Density]:
1.101 g/cm3

[ Boiling Point ]:
244.7ºC at 760 mmHg

[ Molecular Formula ]:
C10H12O2

[ Molecular Weight ]:
164.20100

[ Flash Point ]:
107.8ºC

[ Exact Mass ]:
164.08400

[ PSA ]:
18.46000

[ LogP ]:
1.60200

[ Vapour Pressure ]:
0.0467mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.522(lit.)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
JH6768000
CHEMICAL NAME :
1,3-Dioxolane, 2-benzyl-
CAS REGISTRY NUMBER :
101-49-5
BEILSTEIN REFERENCE NO. :
0117974
LAST UPDATED :
199709
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C10-H12-O2
MOLECULAR WEIGHT :
164.22
WISWESSER LINE NOTATION :
T5O COTJ B1R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 14,827,1976
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
2600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 14,827,1976

Safety Information

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26;S37/S39

[ RTECS ]:
JH6768000

[ HS Code ]:
2932999099

Synthetic Route

Precursor & DownStream

Precursor

  • Phenylacetaldehyde
  • Ethylene glycol
  • 2-Benzyl-1,3-oxathiolane
  • Phenylacetylene
  • (2,2-Dimethoxyethyl)benzene
  • Phenylboronic acid
  • phenylene-ethylene
  • 1,1-Diphenylacetone

DownStream

  • 2-METHOXY-1,3-DIOXOLANE
  • 4-benzylbenzonitrile
  • Bibenzyl
  • Toluene
  • 1-methyl-4-phenylpyrazole
  • (2,2-Dimethoxyethyl)benzene
  • 1,3-Dithiane,2-(phenylmethyl)-
  • Phenethyl alcohol
  • 2-(2-phenylethoxy)ethanol
  • 2-chloroethyl 2-phenylacetate

Customs

[ HS Code ]: 2932999099

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%


Related Compounds

  • 4-Methyl-2-benzyl-1,3-dioxolane
  • 4-Phenyl-2-benzyl-1,3-dioxolane
  • 4,5-Dimethyl-2-benzyl-1,3-dioxolane
  • ethyl 2-benzyl-1,3-dioxolane-2-propionate
  • Methyl 2-benzyl-1,3-dioxolane-2-propionate
  • methyl 2-benzyl-1,3-dioxolane-2-propionate
  • 1-(2-Methoxybutyl)cyclopropan-1-amine
  • rac-(1R,2R)-2-(4-methyl-1,3-thiazol-5-yl)cyclopropan-1-amine
  • rel-(1R,3S,4S)-3,4-Dichlorocyclohexanecarboxylic acid
  • 2-(2-Methylpropoxy)pyridine-3,4-diamine
  • 2-(Propan-2-yloxy)pyridine-3,4-diamine
  • 2-(Cyclopropylmethoxy)pyridine-3,4-diamine
  • 2-Propoxypyridine-3,4-diamine
  • 2-(2,2-Difluoroethoxy)pyridine-3,4-diamine
  • 2-(Oxetan-3-yloxy)pyridine-3,4-diamine
  • (S)-tert-butyl4-amino-2-oxopyrrolidine-1-carboxylate
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