2-Benzylpyridine

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Names

[ CAS No. ]:
101-82-6

[ Name ]:
2-Benzylpyridine

[Synonym ]:
2-Benzyl-pyridine
2-PHENYLPYRIDYLMETHANE
2-benzyl-pyridin
2-benzylpridine
Pyridine, 2-benzyl-
Pyridine, 2- (phenylmethyl)-
2-Benzylpyridine
MFCD00006352
benzyl-2-pyridine
2-(PHENYLMETHYL)PYRIDINE
CDD 3529
EINECS 202-979-1
bpmo
Pyridine, 2-(phenylmethyl)-
Pyridine,2-benzyl

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
276.0±0.0 °C at 760 mmHg

[ Melting Point ]:
8-10 °C(lit.)

[ Molecular Formula ]:
C12H11N

[ Molecular Weight ]:
169.222

[ Flash Point ]:
125.0±0.0 °C

[ Exact Mass ]:
169.089142

[ PSA ]:
12.89000

[ LogP ]:
2.71

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.576

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
US2620000
CHEMICAL NAME :
Pyridine, 2-benzyl-
CAS REGISTRY NUMBER :
101-82-6
BEILSTEIN REFERENCE NO. :
0115875
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C12-H11-N

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1500 mg/kg
TOXIC EFFECTS :
Behavioral - tremor Behavioral - convulsions or effect on seizure threshold Cardiac - pulse rate increase, without fall in BP
REFERENCE :
AEPPAE Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. (Berlin, Ger.) V.110-253, 1925-66. For publisher information, see NSAPCC. Volume(issue)/page/year: 227,129,1955

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
2810

[ WGK Germany ]:
3

[ RTECS ]:
US2620000

[ Packaging Group ]:
I; II; III

[ Hazard Class ]:
6.1

[ HS Code ]:
29333999

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Bromopyridine
  • (C6H5CH2)Ti(O-i-Pr)3
  • Chlorobenzene
  • Iodobenzene
  • 6-phenylhex-5-ynal oxime
  • Bromobenzene
  • 2-Benzoylpyridine
  • 2-Chloropyridine
  • Benzylmagnesium chloride

DownStream

  • 2-benzyl-1-methyl-3,6-dihydro-2H-pyridine
  • Pyridinium,1-(2-oxo-2-phenylethyl)-2-(phenylmethyl)-, bromide (1:1)
  • 2-(4-AMINOBENZYL)PYRIDINE
  • 2-Benzylpiperidine
  • Pyridine,2-(diphenylmethyl)-
  • 1,2-dibenzylpyridin-1-ium,bromide
  • Hexamethyldisilazane
  • 2-Picolinic acid
  • N-Methylbiphenyl-2-amine

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Copper-catalyzed α-methylenation of benzylpyridines using dimethylacetamide as one-carbon source.

Org. Lett. 16(7) , 2050-3, (2014)

The direct α-methylenation of benzylpyridines was achieved using N,N-dimethylacetamide (DMA) as a one-carbon source under copper catalysis. An intermediary species was detected at an early stage, and ...

Ruthenium(II) complexes of 2-benzoylpyridine-derived thiosemicarbazones with cytotoxic activity against human tumor cell lines.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 69(4) , 1073-6, (2008)

Reaction of [RuCl(3)(dppb)H(2)O] (dppb=1,4 bis(diphenylphospine)butane) with 2-benzoylpyridine thiosemicarbazone (H2Bz4DH) and its N(4)-methyl (H2Bz4M) and N(4)-phehyl (H2Bz4Ph) derivatives gave [RuCl...


More Articles

Related Compounds

  • sodium 2-benzylpyridine
  • 2-benzylpyridine N-oxide
  • lithium 2-benzylpyridine
  • 3-AMINO-2-BENZYLPYRIDINE
  • 2-benzylpyridine ethiodide
  • 2-benzylpyridine methiodide
  • N-([2,3'-bipyridin]-5-ylmethyl)-4-(pyrrolidin-1-ylsulfonyl)benzamide
  • 1-([2,3'-Bipyridin]-5-ylmethyl)-3-(thiophen-2-yl)urea
  • 1-([2,3'-Bipyridin]-5-ylmethyl)-3-(benzo[d][1,3]dioxol-5-ylmethyl)urea
  • N-([2,3'-bipyridin]-5-ylmethyl)-5-methylthiophene-2-sulfonamide
  • N-([2,3'-bipyridin]-5-ylmethyl)naphthalene-1-sulfonamide
  • N-([2,3'-bipyridin]-5-ylmethyl)-3,4-dimethoxybenzenesulfonamide
  • N-([2,3'-bipyridin]-5-ylmethyl)-3-chloro-4-methoxybenzenesulfonamide
  • N-([2,3'-bipyridin]-5-ylmethyl)-1-phenylmethanesulfonamide
  • N-([2,3'-bipyridin]-5-ylmethyl)-1-methyl-1H-imidazole-4-sulfonamide
  • N-([2,3'-bipyridin]-5-ylmethyl)-4'-chloro-[1,1'-biphenyl]-3-sulfonamide
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