tert-butyl-[(1S,2R)-2-[(E)-3-iodo-2-methylprop-2-enyl]cyclohexyl]oxy-dimethylsilane

Names

[ CAS No. ]:
101859-18-1

[ Name ]:
tert-butyl-[(1S,2R)-2-[(E)-3-iodo-2-methylprop-2-enyl]cyclohexyl]oxy-dimethylsilane

[Synonym ]:
Silane,(1,1-dimethylethyl)((2-(3-iodo-2-methyl-2-propenyl)cyclohexyl)oxy)dimethyl-,(1alpha,2beta(E))
(1R*,2S*,(2E))-1-[(tert-butyldimethylsilyl)oxy]-2-(3-iodo-2-methyl-2-propenyl)cyclohexane

Chemical & Physical Properties

[ Density]:
1.19g/cm3

[ Boiling Point ]:
354.3ºC at 760 mmHg

[ Molecular Formula ]:
C16H31IOSi

[ Molecular Weight ]:
394.40700

[ Flash Point ]:
168.1ºC

[ Exact Mass ]:
394.11900

[ PSA ]:
9.23000

[ LogP ]:
6.29590

[ Vapour Pressure ]:
6.92E-05mmHg at 25°C

[ Index of Refraction ]:
1.5

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • tert-Butyldimethylsilyl chloride
  • (1R,2S)-2-prop-2-ynylcyclohexan-1-ol
  • trimethylaluminum
  • tert-butyl-dimethyl-[(1R,2S)-2-prop-2-ynylcyclohexyl]oxysilane

DownStream

  • tert-butyl-dimethyl-[(1S,2R)-2-[(2E,5E)-2-methyldodeca-2,5-dienyl]cyclohexyl]oxysilane
  • tert-butyl-dimethyl-[(1S,2R)-2-[(E)-2-methyldodec-2-en-5-ynyl]cyclohexyl]oxysilane
  • (1S,2R)-2-[(2E,5E)-2-methyldodeca-2,5-dienyl]cyclohexan-1-ol