Thiocarbanilide

Names

[ CAS No. ]:
102-08-9

[ Name ]:
Thiocarbanilide

[Synonym ]:
N,N′-diphenylthiourea
Thiocarbanilide
MFCD00004921
N,N'-Diphenylthiourea
Diphenylthiourea
EINECS 203-004-2
1,3-Diphenylthiourea
Thiourea, N,N'-diphenyl-

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
348.7±25.0 °C at 760 mmHg

[ Melting Point ]:
152-155 °C(lit.)

[ Molecular Formula ]:
C₁₃H₁₂N₂S

[ Molecular Weight ]:
228.313

[ Flash Point ]:
164.7±23.2 °C

[ Exact Mass ]:
228.072113

[ PSA ]:
56.15000

[ LogP ]:
2.34

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.749

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
<0.01 g/100 mL at 19 ºC

MSDS

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H300

[ Precautionary Statements ]:
P301 + P310 + P330

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R25

[ Safety Phrases ]:
S36/37/39-S45-S24/25

[ RIDADR ]:
UN 2811 6.1/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
FE1225000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

morpholine
Rhodanine
1,3-Diphenylurea
Phenyl isothiocyanate
Carbon disulphide
N-Phenylhydroxylamine
Disodium carbonotrithioate
N,N'-Thiocarbonyldiimidazole

DownStream

(Phenylamino)(phenylimino)methanesulfonic acid
2-Mercaptobenzimidazole
2,4-dithio-5-nitropyrimidine
Benzenamine,N,N'-methanetetraylbis-
Hydrazinecarbothioamide,N,2-diphenyl-
4-(6-Methyl-2-benzothiazolyl)benzeneamine
1,2-Hydrazinedicarbothioamide,N1,N2-diphenyl-
Carbamothioicacid, N-phenyl-, O-(1-methylethyl) ester
2-Phenyl-isoindole-1,3-dione
carbonyl sulfide

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Occupational rubber glove allergy: results of the Information Network of Departments of Dermatology (IVDK), 1995-2001.

Contact Dermatitis 48(1) , 39-44, (2003)

About 21% of the patients with occupational contact dermatitis registered in the Information Network of Departments of Dermatology (IVDK) in the years 1995-2001 were patch tested due to suspected rubb...

Study of a reaction between 2,3-dichloro-1,4-naphthoquinone and N,N'-diphenyl thiourea involving an EDA adduct as intermediate.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 60(7) , 1641-7, (2004)

The reaction between 2,3-dichloro-1,4-naphthoquinone and N,N'-diphenyl thiourea in acetonitrile medium, which yields the product, 2,3-(N,N'-diphenylthioureylene)-naphtho-1,4-quinone has been found to ...

Diphenylthiourea, a common rubber chemical, is bioactivated to potent skin sensitizers.

Chem. Res. Toxicol. 24(1) , 35-44, (2011)

Diphenylthiourea (DPTU) is a known skin sensitizer commonly used as a vulcanization accelerator in the production of synthetic rubber, for example, neoprene. The versatile usage of neoprene is due to ...