3,4-Dihydroxyphenylacetic acid

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Names

[ CAS No. ]:
102-32-9

[ Name ]:
3,4-Dihydroxyphenylacetic acid

[Synonym ]:
Benzeneacetic acid, 3,4-dihydroxy-
DOPAC
Benzeneacetic acid,3,4-dihydroxy
3,4-dihydroxy-1-benzeneacetic acid
3,4-dihydroxyphenylacetic acid
(3,4-dihydroxyphenyl)-Acetic acid
Homoprotocatechuic acid
4-Carboxymethylpyrocatechol
3,4-dihydroxyphenyl acetic acid
Pyrocatechol-4-acetic Acid
Benzeneacetic acid, 3,4-dihydroxy- (9CI)
Catechol-4-acetic Acid
(3,4-Dihydroxyphenyl)acetic acid
Dihydroxyphenylacetic acid
MFCD00004338
3,4-Dihydroxyphenylacetate
4-Carboxymethylcatechol
Dopacetic acid
EINECS 203-024-1
Homoprotocatechuate

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
418.4±30.0 °C at 760 mmHg

[ Melting Point ]:
127-130 °C(lit.)

[ Molecular Formula ]:
C8H8O4

[ Molecular Weight ]:
168.147

[ Flash Point ]:
221.0±21.1 °C

[ Exact Mass ]:
168.042252

[ PSA ]:
77.76000

[ LogP ]:
0.17

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

[ Index of Refraction ]:
1.643

[ Storage condition ]:
−20°C

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AH0590000
CHEMICAL NAME :
Acetic acid, (3,4-dihydroxyphenyl)-
CAS REGISTRY NUMBER :
102-32-9
BEILSTEIN REFERENCE NO. :
2211017
LAST UPDATED :
199612
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C8-H8-O4
MOLECULAR WEIGHT :
168.16

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Cytogenetic analysis
TEST SYSTEM :
Rodent - hamster Ovary
DOSE/DURATION :
100 mg/L
REFERENCE :
CALEDQ Cancer Letters (Shannon, Ireland). (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1975- Volume(issue)/page/year: 14,251,1981

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
AH0590000

[ HS Code ]:
2918290000

Synthetic Route

Precursor & DownStream

Precursor

  • 4-Hydroxyphenylacetic acid
  • Vanilpyruvic acid
  • Homovanillic acid
  • 3,4-Dimethoxyphenylacetic acid
  • Benzeneacetonitrile, a-hydroxy-3,4-dimethoxy-
  • 1,3-Benzodioxol-5-ylacetic acid
  • (3,4-DIHYDROXYPHENYL)ACETONITRILE
  • Methyl homoveratrate
  • 10-(2-(3,4-dihydroxyphenyl)acetyl)-1,8-dihydroxyanthracen-9(10H)-one

DownStream

  • 1,3-Benzodioxole-5-aceticacid, methyl ester
  • 3,4-Diethoxyphenylacetic acid
  • protocatechuic acid
  • 3,4-Dimethoxyphenylacetic acid
  • 1,3-Benzodioxol-5-ylacetic acid
  • 3,4-Dimethoxyphenethyl alcohol
  • BENZO[1,3]DIOXOL-5-YL-ACETYL CHLORIDE
  • 2-(3,4-dihydroxyphenyl)-2-hydroxy-acetaldehyde
  • 2-(3,4-Dihydroxyphenyl)ethanol

Customs

[ HS Code ]: 2918290000

[ Summary ]:
HS: 2918290000 other carboxylic acids with phenol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) VAT:17.0% MFN tariff:6.5% General tariff:30.0%

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Related Compounds

  • 3,4-dihydroxyphenylacetic acid
  • 3,4-dihydroxyphenylacetic acid sulfate
  • 3,4-Dihydroxyphenylacetic Acid-13C,18O2
  • 3,4-dihydroxyphenylacetic acid diacetate
  • 3,4-Dihydroxyphenylacetic Acid Methyl Ester
  • 5-S-cysteinyl-3,4-dihydroxyphenylacetic acid
  • Pregn-5-en-20-one, 3b,17-dihydroxy-6,16b-dimethyl-, 3-acetate (7CI,8CI)
  • 4-(3,4-Dimethoxyphenyl)-3-buten-1-amine
  • Mercuric paraben
  • 2-Bromo-6-(chloromethyl)-4-methoxypyridine
  • 1-[2-Bromo-6-(chloromethyl)pyridin-4-YL]ethanone
  • N-(6-methylpyridin-2-yl)pyrrolidine-2-carboxamide
  • tert-butyl rel-(3R,4S)-4-[(benzyloxy)methyl]-3-fluoro-4-methoxypiperidine-1-carboxylate
  • 1-[2-(Chloromethyl)-6-iodopyridin-4-YL]ethanone
  • 2-(Chloromethyl)-6-iodo-4-(trifluoromethyl)pyridine
  • 1-(Tetrahydrofuran-3-yl)cyclobutane-1-carboxylic acid
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