(1S)-1-[2,4,6-tri(propan-2-yl)phenyl]ethanol

Names

[ CAS No. ]:
102225-88-7

[ Name ]:
(1S)-1-[2,4,6-tri(propan-2-yl)phenyl]ethanol

[Synonym ]:
fs-0002

Chemical & Physical Properties

[ Melting Point ]:
82-86ºC

[ Molecular Formula ]:
C₁₇H₂₈O

[ Molecular Weight ]:
248.40400

[ Exact Mass ]:
248.21400

[ PSA ]:
20.23000

[ LogP ]:
5.11010

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

(S)-2-((1-(2,4,6-triisopropylphenyl)ethoxy)carbonyl)benzoic acid
1,3,5-Triisopropylbenzene
(1S)-1-[2,4,6-tri(propan-2-yl)phenyl]ethanol
2',4',6'-triisopropylacetophenone
1'-(2'',4'',6''-triisopropylphenyl)ethyl acetoxyacetate
1'-(2'',4'',6''-triisopropylphenyl)ethyl 2,2-dihydroxyacetate

DownStream

(1S)-1-[2,4,6-tri(propan-2-yl)phenyl]ethanol
METHYL 8-CHLORO-6-(TRIFLUOROMETHYL)IMIDAZO[1,2-A]PYRIDINE-7-CARBOXYLATE
Benzenemethanamine, α-methyl-2,4,6-tris(1-methylethyl)-, (αR)
Benzenemethanamine,a-methyl-2,4,6-tris(1-methylethyl)-, (aS)

Articles

New asymmetric approach to natural pyrrolizidines: synthesis of (+)-amphorogynine A, (+)-amphorogynine D, and (+)-retronecine.

J. Org. Chem. 70 , 8352-8363, (2005)

Three natural pyrrolizidines, (+)-amphorogynines A and D and (+)-retronecine, have been prepared from a common lactam intermediate. This central compound, in turn, was synthesized in diastereomericall...

A New Asymmetric Carbon-Carbon Bond Forming Reaction: Four-Component Stereoselective Synthesis of (Z)-4,6-Dihydroxy-3-methylalk-2-enyl Methyl Sulfones This work was supported by the Swiss National Science Foundation.

Angew. Chem. Int. Ed. Engl. 39 , 1806, (2000)

Hamel, M., et al.

Tetrahedron Asymmetry 16 , 3406-3415, (2005)

2',4',6'-triisopropylacetophenone
2,4,6-triisopropylbenzenesulfonyltetrazole
1-[2,4,6-tri(propan-2-yl)phenyl]pent-1-en-3-one
methoxy-oxo-[2,4,6-tri(propan-2-yl)phenyl]phosphanium
fluoro-bis[2,4,6-tri(propan-2-yl)phenyl]borane
(4-methoxyphenyl)-[2,4,6-tri(propan-2-yl)phenyl]methanone
AChE-IN-52
6-Bromo-4-chloro-3-ethyl-3H-imidazo[4,5-c]pyridine
2,6-Dibutanoyl-3,5-dihydroxy-4,4-dimethylcyclohexa-2,5-dien-1-one
1-(4-(1-Tosyl-1h-1,2,3-triazol-4-yl)phenyl)ethanone
3-((Tert-butyldimethylsilyl)oxy)-3-methylcyclobutan-1-one
4-(difluoromethyl)-1H-indole-2-carboxylic acid
methyl 5-fluoro-4-(1-hydroxyethyl)-1H-indole-2-carboxylate
6-Fluoro-4-(1-hydroxyethyl)-1H-indole-2-carboxylic acid
methyl 7-fluoro-4-(1-hydroxyethyl)-1H-indole-2-carboxylate
4-Chloro-7-fluoro-1H-indole-2-carbaldehyde

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