2-Bromo-2',4'-difluoroacetophenone

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Names

[ CAS No. ]:
102429-07-2

[ Name ]:
2-Bromo-2',4'-difluoroacetophenone

[Synonym ]:
MFCD00142822
Ethanone, 2-bromo-1-(2,4-difluorophenyl)-
FR CF DV1E
2-Bromo-2′,4′-difluoroacetophenone
2-Bromo-1-(2,4-difluorophenyl)ethanone
2-Bromo-1-(2,4-difluorophenyl)ethan-1-one
α-Bromo-2',4'-difluoroacetophenone
2,4-Difluorophenacyl Bromide
2-Bromo-2,4-difluoroacetophenone
2-Bromo-2',4'-difluoroacetophenone

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
246.1±25.0 °C at 760 mmHg

[ Melting Point ]:
31-35 °C(lit.)

[ Molecular Formula ]:
C8H5BrF2O

[ Molecular Weight ]:
235.025

[ Flash Point ]:
102.6±23.2 °C

[ Exact Mass ]:
233.949173

[ PSA ]:
17.07000

[ LogP ]:
1.91

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.529

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H228-H302-H314

[ Precautionary Statements ]:
P210-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
F:Flammable;C:Corrosive;

[ Risk Phrases ]:
R11;R22;R34

[ Safety Phrases ]:
S16-S26-S36/37/39-S45

[ RIDADR ]:
UN 2925 4.1/PG 2

[ WGK Germany ]:
3

[ HS Code ]:
2914700090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2',4'-Difluoroacetophenone
  • 1,3-Difluorobenzene
  • Bromoacetyl bromide

DownStream

  • 2,4-Difluoro-alpha-(1H-1,2,4-triazolyl)acetophenone
  • 3-(2,4-Difluorophenyl)-3-oxopropanenitrile
  • 2-Acetyloxy-1-(2,4-difluorophenyl)ethanone
  • 2,4-DIFLUOROPHENACYL THIOCYANATE
  • 2-BROMO-4-(2,4-DIFLUOROPHENYL)THIAZOLE

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Related Compounds

  • 2-bromo-2',4'-dichloroacetophenone
  • 2-bromo-2',4',6'-trimethylpropiophenone
  • 2-Bromo-2',4'-dichloroacetophenone
  • 2-Bromo-2',4',6'-triisopropyl-3,6-dimethoxy-1,1'-biphenyl
  • 2-Bromo-2',4',6'-triisopropyl-3-methoxy-6-methyl-1,1'-biphenyl
  • 2-bromo-2',4'-dimethoxyacetophenone
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine