5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde oxime

Names

[ CAS No. ]:
102487-55-8

[ Name ]:
5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde oxime

Chemical & Physical Properties

[ Molecular Formula ]:
C18H35NO6Si

[ Molecular Weight ]:
389.55900

[ Exact Mass ]:
389.22300

[ PSA ]:
78.74000

[ LogP ]:
3.50840

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2,3:5,6-Di-O-isopropylidene-4-O-(tert-butyldimethylsilyl)-aldehydo-D-glucose
  • ((4R,5R)-5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol
  • 4-O-(tert-butyldimethylsilyl)-2,3:5,6-di-O-isopropylidene-aldehydo-D-mannose

DownStream

  • Castanospermine
  • benzyl (((4S,5R)-5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)carbamate
  • benzyl (((4S,5R)-5-((1R,2R)-1-((tert-butyldimethylsilyl)oxy)-2,3-dihydroxypropyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)carbamate
  • (3aS,8S,8aS,9R,9aS)-8-((tert-butyldimethylsilyl)oxy)-9-hydroxy-2,2-dimethylhexahydro-[1,3]dioxolo[4,5-f]indolizin-6(7H)-one