(+)-3-Bromocamphor

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Names

[ CAS No. ]:
10293-06-8

[ Name ]:
(+)-3-Bromocamphor

[Synonym ]:
(+)-3-Bromocamphor
MFCD00003744
(1R,3S,4S)-3-Bromo-1,7,7-trimethylbicyclo-[2.2.1]heptan-2-one
endo-(1R)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
(1R)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
(+)-Camphor Bromide
EINECS 233-652-1
Bicyclo[2.2.1]heptan-2-one, 3-bromo-1,7,7-trimethyl-, (1R)-

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
245.6±23.0 °C at 760 mmHg

[ Melting Point ]:
74-78ºC

[ Molecular Formula ]:
C10H15BrO

[ Molecular Weight ]:
231.130

[ Flash Point ]:
35.8±9.9 °C

[ Exact Mass ]:
230.030624

[ PSA ]:
17.07000

[ LogP ]:
2.42

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.529

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ED6750000
CHEMICAL NAME :
2-Bornanone, 3-bromo-, (1R,3S,4S)-(+)-
CAS REGISTRY NUMBER :
10293-06-8
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C10-H15-Br-O

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,20,1953

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
ED6750000

[ HS Code ]:
2914700090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (+)-Camphor
  • 1,3,3-Trimethyl-2-norbornanone

DownStream

  • (+)-Camphor
  • (1R)-(-)-CAMPHORQUINONE
  • 3-Oxabicyclo[3.2.1]octane-2,4-dione,1,8,8-trimethyl-, (1R,5S)-
  • (+)-Camphoric Acid
  • (+)-3,9-dibromocamphor
  • (+)-P-MENTH-1-ENE
  • 2-[2-(bromomethyl)-2-methyl-3-methylidenecyclopentyl]acetic acid

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Camphor: a chiral starting material in natural product synthesis.

Nat. Prod. Rep. , 253, (1985)

J.H. Hutchinson, T. Money

Can. J. Chem. 65 , 1, (1987)

R.V. Stevens, D.S. Lawrence

Tetrahedron 41 , 93, (1985)


More Articles

Related Compounds

  • (+)-3-bromocamphor-10-sulfonic acid hydr
  • (+)-3-BROMOCAMPHOR-10-SULFONICACIDHYDRATE
  • (+)-3-bromocamphor-10-sulfonic acid hydrate
  • (+)-3-Bromocamphor-8-sulfonic Acid Ammonium Salt
  • [(1R)-(endo,anti)]-(+)-3-bromocamphor-8-sulfonate
  • [(1R)-(endo,anti)]-(+)-3-bromocamphor-8-sulfonate
  • Methyl 4-hydroxy-2-methoxy-6-benzothiazolecarboxylate
  • 5-Methyl-2-(trideuteriomethoxy)pyridin-3-amine
  • 5-(2-Methyl-4-nitrophenoxy)pyrazolo[1,5-a]pyridine
  • 2-Bromo-1,5-diiodo-3-(trifluoromethyl)benzene
  • 7-Hydroxy-5-nitro-2H-benzo[b][1,4]oxazin-3(4H)-one
  • 3-Acetyl-5-iodo-4-methylbenzonitrile
  • 6-Methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazolo[1,5-a]pyridine
  • 4''-Bromo-3-iodo-1,1':4',1''-terphenyl
  • 1-(2-Cyclopropylphenyl)cyclopropane-1-carbonitrile
  • 1-(6-Aminobenzofuran-3-yl)dihydropyrimidine-2,4(1H,3H)-dione
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