1-Carbamoyl-2-phenylhydrazin

Suppliers

Names

[ CAS No. ]:
103-03-7

[ Name ]:
1-Carbamoyl-2-phenylhydrazin

[Synonym ]:
EINECS 203-072-3
MFCD00007942
anilinourea

Chemical & Physical Properties

[ Density]:
1.275g/cm3

[ Melting Point ]:
171-174 °C(lit.)

[ Molecular Formula ]:
C7H9N3O

[ Molecular Weight ]:
151.16600

[ Exact Mass ]:
151.07500

[ PSA ]:
67.15000

[ LogP ]:
1.84600

[ Index of Refraction ]:
1.601

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
FD0575000
CHEMICAL NAME :
Carbamic acid, 2-phenylhydrazide
CAS REGISTRY NUMBER :
103-03-7
BEILSTEIN REFERENCE NO. :
0743311
LAST UPDATED :
199707
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C7-H9-N3-O
MOLECULAR WEIGHT :
151.19
WISWESSER LINE NOTATION :
ZVMMR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
198 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
394 mg/kg/62W-C
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors

MUTATION DATA

TYPE OF TEST :
DNA repair
TEST SYSTEM :
Bacteria - Escherichia coli
DOSE/DURATION :
250 ug/well
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 133,161,1984 *** REVIEWS *** IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 12,177,1976 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 12,177,1976 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
S45-S36/37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
FD0575000

[ HS Code ]:
2928000090

Synthetic Route

Customs

[ HS Code ]: 2928000090

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

New one-pot, efficient, and regioselective method for the synthesis of 3-Trifluoromethyl-1< i> H</i>-1-phenylpyrazoles and alkyl 3-carboxylate analogs. Bonacorso HG, et al.

Tetrahedron Lett. 53(41) , 5488-5491, (2012)


More Articles


Related Compounds

  • 1-Carbamoyl-2-methyl-2-propyl-3-isobutylcarbamoyloxy-propan
  • 1-CARBAMOYL-2,4-DIMETHYL-1,2-EPOXY-3-HYDROXY-1-(METHOXYCARBONYL)PENTANE
  • 1-carbamoyl-2,3-dihydropyrrole-5-carboxylic acid
  • 1-carbamoyl-2-methyl-3-semicarbazono-cyclopentanecarboxylic acid ethyl ester
  • 1-CARBAMOYL-2,3-DIHYDRO-1H-INDOLE-2-CARBOXYLIC ACID
  • (1-carbamoyl-2-phenyl-ethyl)-carbamic acid tert-butyl ester
  • 4-[(1,3-Thiazol-4-yl)methyl]oxolan-3-ol
  • 3-(Trifluoromethyl)cyclohexyl 4-methylbenzene-1-sulfonate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • rac-(3aR,6aR)-2-{2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]butanoyl}-octahydrocyclopenta[c]pyrrole-3a-carboxylic acid
  • 2-cyclopropyl-2-{[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3,3,3-trifluoro-2-methylpropanamido]oxy}acetic acid
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 2-{4-[(1-Cyclobutylaziridin-2-yl)methoxy]-3-fluorophenyl}propan-2-ol
  • 1-[(2S)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)butanoyl]-4,4-difluoropiperidine-3-carboxylic acid
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-