Cinnamyl acetat

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Names

[ CAS No. ]:
103-54-8

[ Name ]:
Cinnamyl acetat

[Synonym ]:
Ciamyl acetate
Acetic acid, cinnamyl ester
Cinnamyl acetate
C6H5CHCHCH2OAc
1-phenyl-3-acetoxyprop-1-ene
CinnaMic acid ester
PhCH=CHCH2OAc
FEMA 2293
PHENYL ALLYL ACETATE
EINECS 203-121-9
Acetic Acid Cinnamyl Ester
3-Phenylprop-2-en-1-yl acetate
MFCD00008722
2-propen-1-ol, 3-phenyl-, acetate
cinnamyl
acetic acid 3-phenylallyl ester
Gui acid ester
CINNAMICACETATE
Cinnamylacetat

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
265.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C11H12O2

[ Molecular Weight ]:
176.212

[ Flash Point ]:
130.5±19.9 °C

[ Exact Mass ]:
176.083725

[ PSA ]:
26.30000

[ LogP ]:
2.62

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.550

[ Storage condition ]:
2-8°C

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GE2275000
CHEMICAL NAME :
Cinnamyl alcohol, acetate
CAS REGISTRY NUMBER :
103-54-8
BEILSTEIN REFERENCE NO. :
2046000
LAST UPDATED :
199701
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C11-H12-O2
MOLECULAR WEIGHT :
176.23
WISWESSER LINE NOTATION :
1VO2U1R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Human - man
REFERENCE :
CTOIDG Cosmetics and Toiletries. (Allured Pub. Corp., POB 318, Wheaton, IL 60189) V.91- 1976- Volume(issue)/page/year: 94(8),41,1979
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
CTOIDG Cosmetics and Toiletries. (Allured Pub. Corp., POB 318, Wheaton, IL 60189) V.91- 1976- Volume(issue)/page/year: 94(8),41,1979
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - guinea pig
REFERENCE :
CTOIDG Cosmetics and Toiletries. (Allured Pub. Corp., POB 318, Wheaton, IL 60189) V.91- 1976- Volume(issue)/page/year: 94(8),41,1979 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3300 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 11,1063,1973
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4750 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
VPITAR Voprosy Pitaniya. Problems of Nutrition. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1932-41; V.11- 1952- Volume(issue)/page/year: 33(5),48,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PHMCAA Pharmacologist. (American Soc. for Pharmacology and Experimental Therapeutics, 9650 Rockville Pike, Bethesda, MD 20014) V.1- 1959- Volume(issue)/page/year: 3,62,1961
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
4750 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
VPITAR Voprosy Pitaniya. Problems of Nutrition. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1932-41; V.11- 1952- Volume(issue)/page/year: 33(5),48,1974 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 19640 No. of Facilities: 35 (estimated) No. of Industries: 2 No. of Occupations: 29 No. of Employees: 4144 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 19640 No. of Facilities: 49 (estimated) No. of Industries: 3 No. of Occupations: 9 No. of Employees: 2887 (estimated) No. of Female Employees: 939 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36

[ Safety Phrases ]:
S26-S37/39-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
1

[ RTECS ]:
GE2275000

[ HS Code ]:
2915390090

Synthetic Route

Precursor & DownStream

Precursor

  • Cinnamyl alcohol
  • Ethanoic anhydride
  • phenylpropyne
  • acetic acid
  • Allylbenzene
  • Allyl acetate
  • (Diacetoxyiodo)benzene
  • Phenylboronic acid
  • alpha-vinylbenzyl acetate
  • Ethyl acetoacetate

DownStream

  • β-Methylstyrene
  • Allylbenzene
  • 4-methyl-1-phenyl-1,5-hexadiene
  • (2E)-3-Phenyl-2-propen-1-yl formate
  • 1-Naphthyl acetate
  • Benzenepropanol,1-acetate
  • n-propylbenzene
  • Cinnamyl alcohol
  • tert-butyl N-[(1R)-1-phenylprop-2-enyl]carbamate
  • Boc-R-3-amino-3-phenylpropan-1-ol

Customs

[ HS Code ]: 2915390090

[ Summary ]:
2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%

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Related Compounds

  • cinnamyl acetate
  • Cinnamyl acetate
  • (Z)-cinnamyl acetate
  • α-N-AMYL CINNAMYL ACETATE
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  • (3-trifluoromethyl)cinnamyl acetate
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  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • Tert-butyl [1-(phenylacetyl)piperidin-4-yl]carbamate
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  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • N-(5-(2,5-dichlorophenyl)-1,3,4-oxadiazol-2-yl)-4-(ethylsulfonyl)benzamide
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