Formamide, N-phenyl-

Names

[ CAS No. ]:
103-70-8

[ Name ]:
Formamide, N-phenyl-

[Synonym ]:
N-Phenylformamide
ForManilide
EINECS 203-136-0
MFCD00003276

Chemical & Physical Properties

[ Density]:
1.144 g/mL at 25 °C(lit.)

[ Boiling Point ]:
166 °C14 mm Hg(lit.)

[ Melting Point ]:
46-48 °C(lit.)

[ Molecular Formula ]:
C₇H₇NO

[ Molecular Weight ]:
121.13700

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
121.05300

[ PSA ]:
29.10000

[ LogP ]:
1.96380

[ Vapour Pressure ]:
0.00662mmHg at 25°C

[ Index of Refraction ]:
1.594

[ Storage condition ]:
0-10°C

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: BY1780000

CHEMICAL NAME :: Aniline, N-formyl-

CAS REGISTRY NUMBER :: 103-70-8

BEILSTEIN REFERENCE NO. :: 0906934

LAST UPDATED :: 199710

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C7-H7-N-O

MOLECULAR WEIGHT :: 121.15

WISWESSER LINE NOTATION :: VHMR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 400 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: XPHBAO U.S. Public Health Service, Public Health Bulletin. (Washington, DC) Volume(issue)/page/year: 271,19,1941

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 400 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - muscle weakness Lungs, Thorax, or Respiration - respiratory stimulation

REFERENCE :: XPHBAO U.S. Public Health Service, Public Health Bulletin. (Washington, DC) Volume(issue)/page/year: 271,19,1941

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Amphibian - frog

DOSE/DURATION :: 800 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: XPHBAO U.S. Public Health Service, Public Health Bulletin. (Washington, DC) Volume(issue)/page/year: 271,19,1941

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
22

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ RTECS ]:
BY1780000

[ HS Code ]:
2924299090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

ZEKE photoelectron spectroscopy of the cis and trans isomers of formanilide.

Angew. Chem. Int. Ed. Engl. 41(1) , 166-8, (2002)

Phosphazene base-catalyzed condensation of trimethylsilylacetate with carbonyl compounds.

Chem. Commun. (Camb.) (29) , 3128-30, (2006)

The t-Bu-P4 base was found to be an excellent catalyst for the condensation of trimethylsilylacetate or trimethylacetonitrile with carbonyl compounds to form functionalized alkenes and beta-enaminoest...

Isomer selective infrared spectroscopy of supersonically cooled cis- and trans-N-phenylamides in the region from the amide band to NH stretching vibration.

Phys. Chem. Chem. Phys. 11(29) , 6098-106, (2009)

We measured the infrared (IR) spectra of supersonically cooled N-phenylformamide (formanilide) and N-phenylacetamide (acetanilide) in the amide band and X-H stretch vibration regions by using IR-UV de...

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