4-Bromoacetanilide

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Names

[ CAS No. ]:
103-88-8

[ Name ]:
4-Bromoacetanilide

[Synonym ]:
Acetamide, N-(p-bromophenyl)-
N-Acetyl-p-bromoaniline
4‘-Bromoacetanilide
N-Acetyl-4-bromoaniline
acetanilide, 4'-bromo-
EINECS 203-154-9
N-(4-Bromophenyl)acetamide
N1-(4-bromophenyl)acetamide
Acetamide, N-(4-bromophenyl)-
4′-Bromoacetanilide
Acetanilide, p-bromo-
MFCD00000092
4'-bromoacetanilide
N-(4-Bromo-phenyl)-acetamide
UNII-4KB44F25A3

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
353.4±25.0 °C at 760 mmHg

[ Melting Point ]:
165-169 °C(lit.)

[ Molecular Formula ]:
C₈H₈BrNO

[ Molecular Weight ]:
214.059

[ Flash Point ]:
167.6±23.2 °C

[ Exact Mass ]:
212.978912

[ PSA ]:
29.10000

[ LogP ]:
2.29

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.612

[ Stability ]:
Stable. Incompatible with strong oxidizing agents.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AD9625000

CHEMICAL NAME :: Acetanilide, 4'-bromo-

CAS REGISTRY NUMBER :: 103-88-8

BEILSTEIN REFERENCE NO. :: 2208091

LAST UPDATED :: 199701

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C8-H8-Br-N-O

MOLECULAR WEIGHT :: 214.08

WISWESSER LINE NOTATION :: ER DMV1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,10,1953

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 250 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
2811

[ WGK Germany ]:
3

[ RTECS ]:
AD9625000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
2924299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

acetic acid
4-Bromoaniline
Acetyl chloride
Ethanoic anhydride
Acetamide
1-Bromo-4-iodobenzene
Acetanilide
1-(4-Bromophenyl)ethanone
Ethanethioamide,N-(4-bromophenyl)-

DownStream

4-Bromo-N-phenylaniline
4-CYANOACETANILIDE
1-Bromo-4-nitrobenzene
4-Bromo-2-fluoroacetanilide
6-Bromo-2-methylbenzo[d]thiazole
2-acetamido-5-bromobenzoic acid
N-Acetylanthranilic acid
4-Cyanophenyl isocyanate
Bromine
Ethanethioamide,N-(4-bromophenyl)-

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

LC-ESI-MS/MS determination of phenylurea and triazine herbicides and their dealkylated degradation products in oysters.

J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 838(2) , 96-106, (2006)

A method was developed for the determination of several phenylurea and triazine herbicides and their transformation products in oysters at the low microg/kg level. Pressurised liquid extraction (PLE) ...

¹H NMR relaxivity of aqueous suspensions of titanium dioxide nanoparticles coated with a gadolinium (III) chelate of a DOTA-monoamide with a phenylphosphonate pendant arm. Rehor I, et al.

J. Mater. Chem. 19(10) , 1494-1500, (2009)