4'-Methylacetanilide

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Names

[ CAS No. ]:
103-89-9

[ Name ]:
4'-Methylacetanilide

[Synonym ]:
Acetamide, N- (4-methylphenyl)-
N-Acetyl-p-toluidide
(1E)-N-(4-Methylphenyl)ethanimidic acid
4'-methylacetanilide
p-Acetotoluidine
4-(N-Acetyl)aminotoluene
4-METHYLACETANILIDE
Acetyl-p-toluidine
p-toluidine, N-acetyl-
N-(4-Methylphenyl)acetamide
p-Acetotoluidide
Acetamide, N-(4-methylphenyl)-
4-Acetotoluide
1-Acetamido-4-methylbenzene
p-Acetotoluide
N-ACETYL-PARA-TOLUIDINE
4-Acetotoluidide
4-Acetamidotoluene
EINECS 203-155-4
UNII-N36D4JN82T
4′-Methylacetanilide
MFCD00008677
Ethanimidic acid, N-(4-methylphenyl)-, (1E)-
4-(Acetylamino)toluene
p-Acetamidotoluene
N-Acetyl-p-toluidine

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
281.6±33.0 °C at 760 mmHg

[ Melting Point ]:
149-151 °C(lit.)

[ Molecular Formula ]:
C9H11NO

[ Molecular Weight ]:
149.190

[ Flash Point ]:
166.1±14.6 °C

[ Exact Mass ]:
149.084061

[ PSA ]:
29.10000

[ LogP ]:
2.12

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.516

[ Water Solubility ]:
1 g/L (25 ºC)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AN2930000
CHEMICAL NAME :
p-Acetotoluidide
CAS REGISTRY NUMBER :
103-89-9
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C9-H11-N-O
MOLECULAR WEIGHT :
149.21
WISWESSER LINE NOTATION :
1VMR D1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
980 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 19,20,1971

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
AN2930000

[ HS Code ]:
29242995

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Ethanone, 1-(4-methylphenyl)-, oxime, (1E)- (9CI)
  • Ethanoic anhydride
  • p-Toluidine
  • Acetamide
  • 4-Iodotoluene
  • 4'-Methylacetophenone
  • acetic acid
  • 4-Chlorotoluene
  • 4-Nitrotoluene
  • Acetyl chloride

DownStream

  • 1,2-Dibromo-4-methyl-5-nitrobenzene
  • N-(4-methylphenyl)-N-nitroso-acetamide
  • 1,2-Dibromo-4-methylbenzene
  • 4-(Dimethylamino)benzoyl chloride
  • 4'-fluoroacetanilide
  • N-(4-methylphenyl)heptanamide
  • Acetamide,N-(4-methyl-3,6-dioxo-1,4-cyclohexadien-1-yl)-
  • 5-acetylamino-2-methylphenyl acetate
  • N-chloro-N-(4-methylphenyl)acetamide
  • 2-Ethylaminotoluene

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

An efficient synthesis of stable phosphorus ylides derived from triphenylphosphine, dialkyl acetylenedicarboxylates, and an NH-Acid.

Phosphorus. Sulfur. Silicon Relat. Elem. 181(4) , 865-877, (2006)


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Related Compounds

  • N-chloro-4'-methylacetanilide
  • 2-Chloro-4'-methylacetanilide
  • 2'-bromo-4'-methylacetanilide
  • 2'-methoxy-4'-methylacetanilide
  • 3'-acetoxy-4'-methylacetanilide
  • 3'-Isopropyl-4'-methylacetanilide
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine