(1R)-(-)-CAMPHORQUINONE

Names

[ CAS No. ]:
10334-26-6

[ Name ]:
(1R)-(-)-CAMPHORQUINONE

[Synonym ]:
EINECS 220-446-1
MFCD00082863
(1R)-(-)-2,3-Bornanedione
D-Camphoroquinone
(1R)-(-)-CAMPHORQUINONE

Chemical & Physical Properties

[ Density]:
1.098g/cm3

[ Boiling Point ]:
226.5ºC at 760mmHg

[ Melting Point ]:
200-203ºC

[ Molecular Formula ]:
C₁₀H₁₄O₂

[ Molecular Weight ]:
166.21700

[ Flash Point ]:
83ºC

[ Exact Mass ]:
166.09900

[ PSA ]:
34.14000

[ LogP ]:
1.58070

[ Vapour Pressure ]:
0.0817mmHg at 25°C

[ Index of Refraction ]:
1.5

MSDS

Safety Information

[ Symbol ]:

GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H334

[ Precautionary Statements ]:
P261-P284-P301 + P312 + P330-P304 + P340-P342 + P311

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2914299000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

(+)-Camphor
1,7,7-trimethyl-2,3-bis(trimethylsiloxy)bicyclo[2.2.1]hept-2-ene
(±)-Camphor
(+)-3-Bromocamphor
(1S,4R)-3,3-ethylenedioxy-4,7,7-trimethylbicyclo[2.2.1]heptan-2-one
(+)-Camphoric Acid
diethyl (1R,3S)-1,2,2-trimethylcyclopentane-1,3-dicarboxylate
anti-(1R)-(+)-Camphorquinone 3-Oxime
d-camphor N-nitroimine

DownStream

diethoxymethane
(+/-)-Camphor
(1S)-(+)-camphorquinone
(+)-Camphoric Acid
1,1,2-trimethylcyclopentane

Customs

[ HS Code ]: 2914299000

[ Summary ]:
2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Reduction of lipid peroxidation products and advanced glycation end-product precursors by cyanobacterial aldo-keto reductase AKR3G1—a founding member of the AKR3G subfamily.

FASEB J. 29(1) , 263-73, (2015)

The purpose of this study was to investigate the origin and function of the aldo-keto reductase (AKR) superfamily as enzymes involved in the detoxification of xenobiotics. We used the cyanobacterium S...

Tetrahedron Asymmetry 17 , 1179, (2006)

(1R,4S)-3-hydroxyimino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
[(1R,3S,4R)-3-Hydroxy-4,7,7-trimethylbicyclo[2.2.1]hept-2-yl]acet ic acid
(1R,4S)-2,2:3,3-bis(ethylenedioxy)-1,7,7-trimethylbicyclo[2.2.1]heptane
(1R,4S,5S,6S)-4-[2-(3-methyldiazirin-3-yl)ethylsulfanyl]-7-oxabicyclo[4.1.0]hept-2-en-5-ol
[(1R,9aR)-5-methyl-2,3,4,6,7,8,9,9a-octahydro-1H-quinolizin-5-ium-1-yl] butanoate,bromide
(R)-1-(4-chlorophenyl)-N-methylethanamine
4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
N-(5-chloro-2-methoxy-phenyl)-2-(1-phenylpyrazolo[3,4-d]pyrimidin-4-yl)sulfanyl-acetamide
2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
(4-Methyl-tetrahydro-furan-2-yl)-methanol
N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
tert-Butyl-DL-alanine
N-(3-fluorophenyl)-2-(2-{[(4-methylphenyl)methyl]sulfanyl}-1,3-thiazol-4-yl)acetamide