cis-Anethol

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Names

[ CAS No. ]:
104-46-1

[ Name ]:
cis-Anethol

[Synonym ]:
Benzene, 1-methoxy-4-[(1E)-1-propen-1-yl]-
Benzene, 1-methoxy-4- (1-propenyl)-, (E)-
trans-4-(1-Propenyl)anisole
trans-p-Propenylanisole
(E)-1-methoxy-4-(prop-1-en-1-yl)benzene
1-methoxy-4-[(1E)-prop-1-en-1-yl]benzene
trans-4-Propenylanisole
Anise camphor
1-Methoxy-4-[(1E)-1-propen-1-yl]benzene
Nauli gum
p-Anethole
Anethole, trans-
Isoestragole
trans-Anethol
p-1-Propenylanisole
p-propenylanisole
cis-Anethol
benzene, 1-methoxy-4-[(1E)-1-propenyl]-
(E)-1-Methoxy-4-(1-propenyl)benzene
trans-1-(p-Methoxyphenyl)-1-propene
trans-p-Methoxy-β-methylstyrene
1-Methoxy-4-(prop-1-en-1-yl)benzene
MFCD00009284
p-Methoxy-β-methylstyrene
(E)-1-(4-Methoxyphenyl)propene
trans-p-Anethole
Methoxy-4-propenylbenzene
OIL OF ANISEED
p-(1-Propenyl)anisole
trans-1-(4-Methoxyphenyl)-1-propene
1-Méthoxy-4-[(1E)-1-propèn-1-yl]benzène
trans-1-(p-Methoxyphenyl)propene
Anethole
Methyl 4-[(1E)-prop-1-en-1-yl]phenyl ether
trans-1-Methoxy-4-(1-propenyl)benzene
EINECS 224-052-0
cis-Anethol

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
237.5±9.0 °C at 760 mmHg

[ Melting Point ]:
20-21 °C(lit.)

[ Molecular Formula ]:
C10H12O

[ Molecular Weight ]:
148.202

[ Flash Point ]:
90.6±0.0 °C

[ Exact Mass ]:
148.088821

[ PSA ]:
9.23000

[ LogP ]:
3.17

[ Vapour Pressure ]:
0.1±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.545

[ Storage condition ]:
2-8°C

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BZ8925000
CHEMICAL NAME :
Anisole, p-propenyl-
CAS REGISTRY NUMBER :
104-46-1
BEILSTEIN REFERENCE NO. :
0774229
LAST UPDATED :
199701
DATA ITEMS CITED :
12
MOLECULAR FORMULA :
C10-H12-O
MOLECULAR WEIGHT :
148.22
WISWESSER LINE NOTATION :
2U1R DO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2090 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - coma
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 2,327,1964
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
70 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 17,497,1969
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3050 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - coma
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 2,327,1964
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
593 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
YKKZAJ Yakugaku Zasshi. Journal of Pharmacy. (Nippon Yakugakkai, 2-12-15 Shibuya, Shibuya-ku, Tokyo 150, Japan) No.1- 1881- Volume(issue)/page/year: 104,793,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 11,863,1973
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
2160 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity)
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 2,327,1964
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - wild bird species
DOSE/DURATION :
316 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 12,355,1983 ** TUMORIGENIC DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2400 mg/kg/8W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors
REFERENCE :
CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year: 33,3069,1973 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M1381 No. of Facilities: 38 (estimated) No. of Industries: 3 No. of Occupations: 8 No. of Employees: 511 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M1381 No. of Facilities: 4061 (estimated) No. of Industries: 49 No. of Occupations: 46 No. of Employees: 58125 (estimated) No. of Female Employees: 15589 (estimated)

Safety Information

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R43

[ Safety Phrases ]:
S36/37

[ WGK Germany ]:
2

[ RTECS ]:
BZ9275000

[ HS Code ]:
2909309090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Chloro-4-methoxybenzene
  • Allyltributyltin
  • 1-bromopropene
  • magnesium,methoxybenzene,chloride
  • 4-Bromoanisole
  • 4-[(Z)-2-dodecylthioethenyl]anisole
  • METHYLMAGNESIUM BROMIDE
  • Ethyl1-PropenylEther
  • 4-Anisylmagnesium bromide
  • Estragole

DownStream

  • 3-Bromo-4-methoxybenzaldehyde
  • 3-(1-Methyl-1H-pyrrol-2-yl)pyridine
  • p-Anisic acid
  • 2-(4-Methoxyphenyl)-2-oxoacetic acid
  • 4-Methoxybenzaldehyde
  • trans-Anethole
  • (Z)-anethol
  • 3-Buten-2-one,4-(4-methoxyphenyl)-
  • Desmethylanethol trithione
  • Methyl anisate

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Related Compounds

  • cis-Anethol
  • cis-2,5-dimethyl-pyrrolidine
  • cis-3,4-dibromo-3-methylpyrrolidine hydrochloride
  • cis-4,5-Dimethyl-1,3-dioxolane-2-thione
  • cis-Terbinafine Hydrochloride
  • cis-{Pt(NH3)2(O1-DMF)Cl}(1+)
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-{4-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)ethyl]-5,5-dimethylhexanamido}acetic acid
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide