Cinnamyl alcohol

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Names

[ CAS No. ]:
104-54-1

[ Name ]:
Cinnamyl alcohol

[Synonym ]:
cinnamic alcohol
stylone
trans-3-phenyl-2-propen-1-ol
Peruvin
Ciamyl alcohol
STYRYL CARBINOL
Cinnamylalkohol
(E)-cinnamyl alcohol
(E)-3-phenylprop-2-en-1-ol
3-PHENYLALLYLOL
EINECS 203-212-3
(2E)-3-phenylprop-2-en-1-ol
Sterone
MFCD00002921
(2E)-3-Phenyl-2-propen-1-ol
Cinnamyl alcohol
3-phenylprop-2-en-1-ol
3-Phenyl
allylic benzylic alcohol
cinnamyl alcohol, (E)-isomer
Chnnamyl alcohol
cynnamyl alcohol
Styrylicalcohol
3-phenyl-2-propen-1-ol
2-Propen-1-ol, 3-phenyl-, (2E)-

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
250.0±0.0 °C at 760 mmHg

[ Melting Point ]:
30-33 °C(lit.)

[ Molecular Formula ]:
C9H10O

[ Molecular Weight ]:
134.175

[ Flash Point ]:
124.8±14.5 °C

[ Exact Mass ]:
134.073166

[ PSA ]:
20.23000

[ LogP ]:
1.70

[ Vapour density ]:
4.6 (vs air)

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.599

[ Storage condition ]:
2-8°C

[ Stability ]:
Stable. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
1.8 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GE2200000
CHEMICAL NAME :
Cinnamyl alcohol
CAS REGISTRY NUMBER :
104-54-1
BEILSTEIN REFERENCE NO. :
1903999
LAST UPDATED :
199701
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C9-H10-O
MOLECULAR WEIGHT :
134.19
WISWESSER LINE NOTATION :
Q2U1R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2675 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
2675 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
6366 mg/kg/17W-I
TOXIC EFFECTS :
Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other Enzymes

MUTATION DATA

TYPE OF TEST :
DNA repair
TEST SYSTEM :
Bacteria - Bacillus subtilis
DOSE/DURATION :
10 mg/disc
REFERENCE :
OIGZDE Osaka-shi Igakkai Zasshi. Journal of Osaka City Medical Association. (Osaka-shi Igakkai, c/o Osaka-shiritsu Daigaku Igakubu, 1-4-54 Asahi-cho, Abeno-ku, Osaka, 545, Japan) V.24- 1975- Volume(issue)/page/year: 34,267,1985 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83181 No. of Facilities: 163 (estimated) No. of Industries: 6 No. of Occupations: 36 No. of Employees: 8942 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83181 No. of Facilities: 4817 (estimated) No. of Industries: 25 No. of Occupations: 48 No. of Employees: 76974 (estimated) No. of Female Employees: 43896 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H317-H319

[ Precautionary Statements ]:
P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R36;R43

[ Safety Phrases ]:
S26-S36/37-S37/39-S24

[ RIDADR ]:
2811

[ WGK Germany ]:
2

[ RTECS ]:
GE2200000

[ Hazard Class ]:
6.1

[ HS Code ]:
2912299000

Synthetic Route

Precursor & DownStream

Precursor

  • 3-Phenyl-2-propyn-1-ol
  • 3-Phenylpropene-3-ol
  • Benzene, [(1E)-3-(methoxymethoxy)-1-propen-1-yl]
  • Cinnamaldehyde
  • Cinnamic acid
  • Ethyl cinnamate
  • (3-phenyl-prop-2-en-1-oxy)trimethylsilane
  • tert-butyl-dimethyl-(3-phenylprop-2-enoxy)silane
  • Ciprofloxacin Hydrochloride

DownStream

  • bis(3-phenylprop-2-enyl) oxalate
  • 3-Phenylpropene-3-ol
  • Cinnamyl bromide
  • 1H-Benzimidazole,2-(2-phenylethenyl)-
  • (E)-4-(4-NITROPHENYL)-4-OXOBUT-2-ENOICACID
  • phenylene-ethylene
  • β-Methylstyrene
  • Cinnamaldehyde

Customs

[ HS Code ]: 2912299000

[ Summary ]:
2912299000. other cyclic aldehydes without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

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Related Compounds

  • Cinnamyl alcohol
  • Z-cinnamyl alcohol
  • Cinnamyl alcohol,pro
  • Hydrocinnamyl Alcohol
  • 2-nitrocinnamyl alcohol
  • a-Methylcinnamyl Alcohol
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 2-[1-(cyclopropylmethyl)-1H-1,2,3-triazol-4-yl]acetic acid
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • 3-(3-Hydroxy-3-methylbutyl)pyrrolidin-2-one
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 2-Bromo-1-fluoro-4-(1-isocyanatocyclopropyl)benzene
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde