Benzyl formate

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Names

[ CAS No. ]:
104-57-4

[ Name ]:
Benzyl formate

[Synonym ]:
benzyloxycarbonyl
EINECS 203-214-4
Formic acid,benzyl ester
Ameisensaeure-benzylester
Formic acid phenylmethyl ester
MFCD00014128
Formic acid,phenylmethyl ester
Benzyl formiat
Benzyl alcohol,formate
benzylformate
Formic acid, benzyl ester
Formic acid, phenylmethyl ester
phenylmethyl ester of formic acid,benzyl formic ester
Benzyl formate
formic acid benzyl ester
Phenylmethyl formate
Benzyl alcohol, formate
Benzyl methanoate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
203.8±9.0 °C at 760 mmHg

[ Melting Point ]:
4ºC

[ Molecular Formula ]:
C8H8O2

[ Molecular Weight ]:
136.148

[ Flash Point ]:
99.5±9.3 °C

[ Exact Mass ]:
136.052429

[ PSA ]:
26.30000

[ LogP ]:
1.54

[ Vapour Pressure ]:
0.3±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.511

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LQ5400000
CHEMICAL NAME :
Formic acid, benzyl ester
CAS REGISTRY NUMBER :
104-57-4
BEILSTEIN REFERENCE NO. :
2041319
LAST UPDATED :
199709
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C8-H8-O2
MOLECULAR WEIGHT :
136.16
WISWESSER LINE NOTATION :
VHO1R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
DNA repair
TEST SYSTEM :
Bacteria - Bacillus subtilis
DOSE/DURATION :
22 mg/disc
REFERENCE :
OIGZDE Osaka-shi Igakkai Zasshi. Journal of Osaka City Medical Association. (Osaka-shi Igakkai, c/o Osaka-shiritsu Daigaku Igakubu, 1-4-54 Asahi-cho, Abeno-ku, Osaka, 545, Japan) V.24- 1975- Volume(issue)/page/year: 34,267,1985 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - E0379 No. of Facilities: 259 (estimated) No. of Industries: 1 No. of Occupations: 5 No. of Employees: 7246 (estimated) No. of Female Employees: 6082 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312

[ Precautionary Statements ]:
P280

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R21/22

[ Safety Phrases ]:
S36-S36/37

[ RIDADR ]:
NA 1993 / PGIII

[ WGK Germany ]:
1

[ RTECS ]:
LQ5400000

[ HS Code ]:
2915120000

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2915120000

[ Summary ]:
2915120000 salts of formic acid。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Related Compounds

  • benzyl formate dimethyl acetal
  • 2-(2-cyanoacetyl)piperidine-1-benzyl formate
  • α-(bromomethyl)-3,5-dichloro-α-(2,2,2-trichloroethyl)benzyl formate
  • Benzyl alcohol, .alpha.-(1-bromoethyl)-, formate, threo-
  • benzyl (R)-3-(cyanomethyl)piperazine-1-carboxylate
  • benzyl 4-amino-2-Methyl-4-oxobutan-2-ylcarbamate
  • 2-(4-(3-(4-methoxyphenyl)propanamido)phenyl)-N,N-dimethyl-2H-tetrazole-5-carboxamide
  • 2-{1,4-Dioxaspiro[4.4]nonan-2-yl}ethan-1-ol
  • 2-(2-Chloroethyl)-1,4-dioxaspiro[4.4]nonane
  • 5-(Benzylsulfanyl)-1,2-dihydropyrimidin-2-one hydrochloride
  • N-(2-ethoxyphenyl)-4-(pyridin-2-yloxy)piperidine-1-carboxamide
  • Tert-butyl 2-cyano-2-(4-(trifluoromethyl)pyridin-2-yl)acetate
  • 2-Bromo-6-cyanopyridine-4-sulfonyl chloride
  • N-(4-(5-(dimethylcarbamoyl)-2H-tetrazol-2-yl)phenyl)quinoxaline-2-carboxamide
  • 2-Bromo-6-nitropyridine-4-sulfonyl chloride
  • Benzamide, N-[4-[(7-chloro-2,3,4,5-tetrahydro-5-oxo-1H-1-benzazepin-1-yl)carbonyl]-3-methylphenyl]-4-methyl-
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