1,1'-(azodicarbonyl)-dipiperidine

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Names

[ Name ]:
1,1'-(azodicarbonyl)-dipiperidine

[Synonym ]:
Piperidine, 1,1'-[azobis(carbonyl)]bis-
(E)-diazene-1,2-diylbis(piperidin-1-ylmethanone)
1,1'-Azobis(N,N-pentamethyleneformamide)
1,1-(Azodicarbonyl)-Dipiperidine
1,1'-(azodicarbonyl)-dipiperidine
MFCD00010111
(E)-1,2-Diazenediylbis(1-piperidinylmethanone)
Methanone, 1,1'-[(E)-1,2-diazenediyl]bis[1-(1-piperidinyl)-
Piperidine, 1,1'-(azodicarbonyl)bis-
Diazene-1,2-diylbis(piperidin-1-ylmethanone)
(NE)-N-(piperidine-1-carbonylimino)piperidine-1-carboxamide
1,1'-(Azodicarbonyl)dipiperidine
Azodicarboxylic acid dipiperidide

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
366.4±25.0 °C at 760 mmHg

[ Melting Point ]:
132-136 °C(lit.)

[ Molecular Formula ]:
C₁₂H₂₀N₄O₂

[ Molecular Weight ]:
252.313

[ Flash Point ]:
175.4±23.2 °C

[ Exact Mass ]:
252.158630

[ PSA ]:
65.34000

[ LogP ]:
0.99

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.622

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Piperidine
dead

DownStream

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Copper salt catalyzed addition of arylboronic acids to azodicarboxylates.

J. Org. Chem. 70 , 8631, (2005)

The addition of arylboronic acids 1 to azodicarboxylates 2 in the presence of a catalytic amount of a copper salt under mild reaction conditions gives aryl-substituted hydrazines 3 in high yields. The...

Structure--activity relationships of 1beta-methyl-2-(5-phenylpyrrolidin-3-ylthio)carbapenems.

Bioorg. Med. Chem. 10 , 1595, (2002)

Structure--activity relationship studies of 1beta-methyl-2-[(3S,5R)-5-(4-aminomethylphenyl)pyrrolidin-3-ylthio]carbapenems, especially those pertaining to the relationship between antibacterial activi...

Radiosensitization, thiol oxidation, and inhibition of DNA repair by SR 4077.

Radiat. Res. 113 , 346, (1988)

The mechanism of radiosensitization by diazenedicarboxylic acid bis(N),N-piperidide (SR 4077), a less toxic analog of diamide, was studied using Chinese hamster ovary cells. SR 4077 gave an average SE...

4-ethyl-N-(4-ethylpiperazine-1-carbonyl)iminopiperazine-1-carboxamide
1,1'-(p-bromobenzylidene)dipiperidine
1,1'-(Oxydi-2,1-ethanediyl)dipiperidine dihydrochloride
1,1'-[3-(1-Naphtyl)pentane-1,5-diyl]dipiperidine
1,1'-((1S,2S,3R,4R)-3,4-bis(azidomethyl)cyclobutane-1,2-diyl)bis(ethan-1-one)
1,1'-(1-(phenylsulfonyl)-1H-indole-2,3-diyl)bis(ethan-1-ol)
2-{[1-(4-Methylphenyl)ethyl]amino}propane-1,3-diol
2-[(3,3-Dimethylcyclohexyl)amino]propane-1,3-diol
2-[(1-Cyclopropylethyl)amino]propane-1,3-diol
3-(4-amino-3,5-dimethyl-1H-pyrazol-1-yl)-1-methylpyrrolidin-2-one
2-{[(2,3-Dichlorophenyl)methyl]amino}propane-1,3-diol
(2-Ethoxyethyl)[(oxan-4-yl)methyl]amine
5-Bromo-3-(4-aminomethylphenyl)-2-phenyl-1H-pyrrolo[2,3-b]pyridine
1-(2,4-Dichlorophenyl)piperidin-3-amine
5-Ethyl-6-iodo-[1,2,4]triazolo[1,5-a]pyrimidin-7-amine
3-(4-Methoxy-2-methylphenyl)propanal

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