2-Methoxy carbonyl cyclopentanone

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Names

[ Name ]:
2-Methoxy carbonyl cyclopentanone

[Synonym ]:
Cyclopentanecarboxylic acid, 2-oxo-, methyl ester
2-Methoxycarbonylcyclopentanone
Methyl cyclopentanone-2-carboxylate
Methyl 2-oxocyclopentanecarboxylate
2-Oxocyclopentanecarboxylic Acid Methyl Ester
2-Methoxy carbonyl cyclopentanone
Cyclopentanone-2-carboxylic Acid Methyl Ester
methyl 2-oxocyclopentane-1-carboxylate
MFCD00001411
EINECS 233-962-7

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
209.7±33.0 °C at 760 mmHg

[ Molecular Formula ]:
C₇H₁₀O₃

[ Molecular Weight ]:
142.152

[ Flash Point ]:
84.0±25.4 °C

[ Exact Mass ]:
142.062988

[ PSA ]:
43.37000

[ LogP ]:
-0.27

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.468

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Dimethyl adipate
Methyl cyanoformate
Cyclopentanone
Carbon dioxide
methyl iodide
methyl 1-hydroxy-2-oxo-cyclopentanecarboxylate
acrylic acid methyl ester
Dimethyl Carbonate
1-Pyrrolidino-1-cyclopentene

DownStream

2-(3-bromopropyl)cyclopentan-1-one
methyl 1-(bromomethyl)-2-oxocyclopentane-1-carboxylate
2,3,4,5,6,7-hexahydrocyclopenta[b]pyran
Cyclopentanecarboxylic acid, 2-(acetylhydrazono)-, methyl ester, (E)- (9CI)
2-pentyl cyclopentanone
2-Cyclopentene-1-carboxylic acid methyl ester
2-methylidenecyclopentan-1-ol
2-benzylhexanedioic acid
2,3-DIMETHYL-2,3-DINITROBUTANE

Customs

[ HS Code ]: 2918300090

[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Kinetics of monochelation of aqueous chromium (III) by methyl 2-oxocyclopentanecarboxylate. Rojas A, et al.

J. Phys. Org. Chem. 13(2) , 97-104, (2000)

Nickel (I) Salen-Catalyzed Reduction of 1-Haloalkyl-2-oxocycloalkanecarboxylates Three-and Four-Carbon Ring Expansions. Mubarak MS, et al.

J. Electrochem. Soc. 154(11) , F205-F210, (2007)

Aromatase inhibitors: synthesis, biological activity, and structure of 1,2-imidazolylmethylcyclopentanol derivatives.

Chem. Pharm. Bull. 43(12) , 2152-8, (1995)

Two series of 1,2-disubstituted imidazolylmethylcyclopentanol derivatives (5a-d, 10a-d) were prepared by using easily available methyl 2-oxocyclopentanecarboxylate as the starting material. Evaluation...

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methyl 1,3-butadiene-2-carboxylate
METHYL 3-HYDROXY-5-METHOXY-2-THIOPHENECARBOXYLATE
3-(Aminomethyl)-3-(2-nitrophenyl)cyclobutan-1-ol
3-(2,4-dihydroxyphenyl)-1-methyl-1H-pyrazole-5-carboxylic acid
1-{[4-(Propan-2-yl)cyclohexyl]methyl}cyclopropan-1-ol
3-(5-chloro-1H-indol-2-yl)-3-hydroxypropanoic acid
4-[4-Fluoro-2-(trifluoromethyl)phenyl]oxane-2,6-dione
tert-butyl N-[5-(2-amino-3-hydroxypropyl)-2-hydroxy-3-methoxyphenyl]carbamate
3-(2-Bromopropyl)quinoline
1-[2-(2,3-dihydro-1H-inden-2-yl)ethyl]cyclopropan-1-amine
[1-(2,6-Difluoro-4-methoxyphenyl)-2,2-dimethylcyclopropyl]methanol
2-Amino-3-(3-chloro-2-fluorophenyl)-2-methylpropan-1-ol

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