2-Hexanol

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Names

[ CAS No. ]:
105-30-6

[ Name ]:
2-Hexanol

[Synonym ]:
UNII:U8933MB30H
(RS)-2-hexanol
Methylpentanol
2-methylpentan-1-ol
2-Methyl-1-pentanol
Hexan-2-ol
2-methyl-2-propylethanol
1-Pentanol, 2-methyl-
Pentanol, methyl-
2-Propylpropanol
2-methylpentanol
EINECS 203-285-1
MFCD00004745
2-Methylamyl Alcohol
UNII:9CDT0V6T4P
2-Hexanol

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
148.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C6H14O

[ Molecular Weight ]:
102.175

[ Flash Point ]:
50.6±0.0 °C

[ Exact Mass ]:
102.104462

[ PSA ]:
20.23000

[ LogP ]:
1.75

[ Vapour density ]:
3.5 (vs air)

[ Vapour Pressure ]:
1.7±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.414

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SA7175000
CHEMICAL NAME :
1-Pentanol, 2-methyl-
CAS REGISTRY NUMBER :
105-30-6
BEILSTEIN REFERENCE NO. :
1718974
LAST UPDATED :
199710
DATA ITEMS CITED :
18
MOLECULAR FORMULA :
C6-H14-O
MOLECULAR WEIGHT :
102.20
WISWESSER LINE NOTATION :
Q1Y3&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,198,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,198,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Human
DOSE/DURATION :
50 ppm
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - effect, not otherwise specified
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 28,262,1946
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1410 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954
TYPE OF TEST :
LC - Lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>5000 ppm/6H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: 21MAY1971
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>3200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: 21MAY1971
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
3560 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-DENMARK:TWA 25 ppm (100 mg/m3);Skin JAN 1993 OEL-FRANCE:TWA 25 ppm (100 mg/m3);Skin JAN 1993 OEL-THE NETHERLANDS:TWA 25 ppm (100 mg/m3);Skin JAN 1993 OEL-THE PHILIPPINES:TWA 25 ppm (100 mg/m3);Skin JAN 1993 OEL-TURKEY:TWA 25 ppm (100 mg/m3);Skin JAN 1993 OEL-UNITED KINGDOM:TWA 25 ppm (100 mg/m3);STEL 40 ppm;Skin JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X9059 No. of Facilities: 732 (estimated) No. of Industries: 8 No. of Occupations: 11 No. of Employees: 7512 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H302

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
UN 1987 3/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
SA7175000

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2905199090

Synthetic Route

Precursor & DownStream

Precursor

  • UNII:64L45T2504
  • trans-2-Methyl-2-pentenal
  • Methanol
  • pentanol
  • Pent-1-ene
  • carbon monoxide
  • Propionic anhydride
  • 1-Propanol
  • 2-Methylpentanoic acid
  • Ethanol

DownStream

  • 2-Methylpentyl 2-methylpentanoate
  • 2-Methylpentanoic acid
  • UNII:64L45T2504
  • 2-Pentanol
  • Pentan-2-one
  • 3-Methylvaleric Acid
  • 1-BROMO-2-METHYLPENTANE
  • 2-bromo-2-methylpentane
  • 2-Methylpentyl Acetate
  • 2-METHYLPENTENE

Customs

[ HS Code ]: 2905199090

[ Summary ]:
2905199090. saturated monohydric alcohols. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

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